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The principle of minimum energy is essentially a restatement of the second law of thermodynamics. It states that for a closed system, with constant external parameters and entropy, the internal energy will decrease and approach a minimum value at equilibrium. External parameters generally means the volume, but may include other parameters which ...
In the field of computational chemistry, energy minimization (also called energy optimization, geometry minimization, or geometry optimization) is the process of finding an arrangement in space of a collection of atoms where, according to some computational model of chemical bonding, the net inter-atomic force on each atom is acceptably close to zero and the position on the potential energy ...
Planck's radiation equation contained a residual energy factor, one hν / 2 , as an additional term dependent on the frequency ν, which was greater than zero (where h is the Planck constant). It is therefore widely agreed that "Planck's equation marked the birth of the concept of zero-point energy."
By the principle of minimum energy, there are a number of other state functions which may be defined which have the dimensions of energy and which are minimized according to the second law under certain conditions other than constant entropy. These are called thermodynamic potentials. For each such potential, the relevant fundamental equation ...
In 1953, Brillouin derived a general equation [10] stating that the changing of an information bit value requires at least kT ln(2) energy. This is the same energy as the work Leo Szilard's engine produces in the idealistic case, which in turn equals the same quantity found by Landauer.
The minimum total potential energy principle is a fundamental concept used in physics and engineering.It dictates that at low temperatures a structure or body shall deform or displace to a position that (locally) minimizes the total potential energy, with the lost potential energy being converted into kinetic energy (specifically heat).
The concept of free energy was developed by Hermann von Helmholtz, a German physicist, and first presented in 1882 in a lecture called "On the thermodynamics of chemical processes". [1] From the German word Arbeit (work), the International Union of Pure and Applied Chemistry (IUPAC) recommends the symbol A and the name Helmholtz energy . [ 2 ]
The energy spectrum of a system with such discrete energy levels is said to be quantized. In chemistry and atomic physics, an electron shell, or principal energy level, may be thought of as the orbit of one or more electrons around an atom's nucleus. The closest shell to the nucleus is called the "1 shell" (also called "K shell"), followed by ...