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2 NH 3 + H 2 SO 4 → (NH 4) 2 SO 4. A mixture of ammonia gas and water vapor is introduced into a reactor that contains a saturated solution of ammonium sulfate and about 2% to 4% of free sulfuric acid at 60 °C. Concentrated sulfuric acid is added to keep the solution acidic, and to retain its level of free acid.
Ammonium iron(II) sulfate, or Mohr's salt, is the inorganic compound with the formula (NH 4) 2 SO 4 ·Fe(SO 4)·6H 2 O.Containing two different cations, Fe 2+ and NH + 4, it is classified as a double salt of ferrous sulfate and ammonium sulfate.
Ammonium iron(III) sulfate, NH 4 Fe(SO 4) 2 ·12 H 2 O, or NH 4 [Fe(H 2 O) 6](SO 4) 2 ·6 H 2 O, also known as ferric ammonium sulfate (FAS) or iron alum, is a double salt in the class of alums, which consists of compounds with the general formula AB(SO 4) 2 · 12 H 2 O. [2] It has the appearance of weakly violet, octahedrical crystals.
For example, sulfuric acid (H 2 SO 4) is a diprotic acid. Since only 0.5 mol of H 2 SO 4 are needed to neutralize 1 mol of OH −, the equivalence factor is: f eq (H 2 SO 4) = 0.5. If the concentration of a sulfuric acid solution is c(H 2 SO 4) = 1 mol/L, then its normality is 2 N. It can also be called a "2 normal" solution.
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2 NH 3 + SO 2 + H 2 O → (NH 4) 2 SO 3. Ammonium sulfite is produced in gas scrubbers, now obsolete, consisting of ammonium hydroxide to remove sulfur dioxide from emissions from power plants. The conversion is the basis of the Walther Process. The resulting ammonium sulfite can be air oxidized to give ammonium sulfate. [4]