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For other isotopes, the isotopic mass is usually within 0.1 u of the mass number. For example, 35 Cl (17 protons and 18 neutrons) has a mass number of 35 and an isotopic mass of 34.96885. [7] The difference of the actual isotopic mass minus the mass number of an atom is known as the mass excess, [8] which for 35 Cl is –0.03115.
By definition, the atomic mass of carbon-12 is 12 Da, giving a molar mass of 12 g/mol. The number of molecules per mole in a substance is given by the Avogadro constant, exactly 6.022 140 76 × 10 23 mol −1 since the 2019 revision of the SI. Thus, to calculate the stoichiometry by mass, the number of molecules required for each reactant is ...
For example, the relative isotopic mass of a carbon-12 atom is exactly 12. For comparison, the atomic mass of a carbon-12 atom is exactly 12 daltons. Alternately, the atomic mass of a carbon-12 atom may be expressed in any other mass units: for example, the atomic mass of a carbon-12 atom is 1.992 646 882 70 (62) × 10 −26 kg.
In chemistry and physics, the dimensionless mixing ratio is the abundance of one component of a mixture relative to that of all other components. The term can refer either to mole ratio (see concentration ) or mass ratio (see stoichiometry ).
Because a dalton, a unit commonly used to measure atomic mass, is exactly 1/12 of the mass of a carbon-12 atom, this definition of the mole entailed that the mass of one mole of a compound or element in grams was numerically equal to the average mass of one molecule or atom of the substance in daltons, and that the number of daltons in a gram ...
Historically, the mole was defined as the amount of substance in 12 grams of the carbon-12 isotope.As a consequence, the mass of one mole of a chemical compound, in grams, is numerically equal (for all practical purposes) to the mass of one molecule or formula unit of the compound, in daltons, and the molar mass of an isotope in grams per mole is approximately equal to the mass number ...
Since protons and neutrons have approximately the same mass (and the mass of the electrons is negligible for many purposes) and the mass defect of the nucleon binding is always small compared to the nucleon mass, the atomic mass of any atom, when expressed in daltons (making a quantity called the "relative isotopic mass"), is within 1% of the ...
In 1803 John Dalton proposed to use the (still unknown) atomic mass of the lightest atom, hydrogen, as the natural unit of atomic mass. This was the basis of the atomic weight scale. [12] For technical reasons, in 1898, chemist Wilhelm Ostwald and others proposed to redefine the unit of atomic mass as 1 / 16 the mass of an oxygen atom. [13]