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The cathode reaction is 2 Na + + 2 e − → 2Na. The anode reaction is 4 OH − → O 2 + 2 H 2 O + 4 e −. Despite the elevated temperature, some of the water produced remains dissolved in the electrolyte. [4] This water diffuses throughout the electrolyte and results in the reverse reaction taking place on the electrolyzed sodium metal:
In addition, a rocking mechanism (B shown by fulcrum on the left and rotating eccentric on the right) agitates the mercury to transport the dissolved sodium metal from the outside cells to the center cell. The anode reaction in the center cell takes place at the interface between the mercury and the sodium hydroxide solution.
Sodium hydroxide, also known as lye and caustic soda, [1] [2] is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na + and hydroxide anions OH −. Sodium hydroxide is a highly corrosive base and alkali that decomposes lipids and proteins at ambient temperatures and may cause severe ...
Photochemically intercalated sodium ion enhances the photoelectrocatalytic activity of WO 3. [11] Like all the alkali metals, sodium reacts exothermically with water. The reaction produces caustic soda (sodium hydroxide) and flammable hydrogen gas. When burned in air, it forms primarily sodium peroxide with some sodium oxide. [12]
The sodium–mercury amalgam flows to the center cell, where it reacts with water to produce sodium hydroxide and regenerate the mercury. Mercury cell electrolysis, also known as the Castner–Kellner process, was the first method used at the end of the nineteenth century to produce chlorine on an industrial scale.
The reaction between sodium hydroxide and some metals is also hazardous. Aluminium , magnesium , zinc , tin , chromium , brass and bronze all react with lye to produce hydrogen gas. Since hydrogen is flammable , mixing a large quantity of lye with aluminium could result in an explosion.
Sodium hydroxide: Aqueous NaOH −469.15 Sodium hydroxide: Solid NaOH −425.93 Sodium hypochlorite: Solid NaOCl −347.1 Sodium nitrate: Aqueous NaNO 3: −446.2 Sodium nitrate: Solid NaNO 3: −424.8 Sodium oxide: Solid Na 2 O −414.2 Sulfur (monoclinic) Solid S 8: 0.3 Sulfur (rhombic) Solid S 8: 0 Hydrogen sulfide: Gas H 2 S −20.63 Sulfur ...
The aqueous solution in the classical reaction contains glucose, sodium hydroxide and methylene blue. [14] In the first step an acyloin of glucose is formed. The next step is a redox reaction of the acyloin with methylene blue in which the glucose is oxidized to diketone in alkaline solution [6] and methylene blue is reduced to colorless leucomethylene blue.