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The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
In chemical nomenclature, the IUPAC nomenclature of organic chemistry is a method of naming organic chemical compounds as recommended [1] [2] by the International Union of Pure and Applied Chemistry (IUPAC). It is published in the Nomenclature of Organic Chemistry (informally called the Blue Book). [3]
Butyl acetate, an ester derived from a residue of butanol (CH 3 CH 2 CH 2 CH 2 OH) (the butanol residue is butyl group −CH 2 CH 2 CH 2 CH 3) (right side of the picture, blue) and acetic acid CH 3 CO 2 H (left side of the picture, orange). The acidic hydrogen atom (−H) from acetic acid molecule is replaced by the butyl group.
At the time when biologist Carl Linnaeus (1707–1778) published the books that are now accepted as the starting point of binomial nomenclature, Latin was used in Western Europe as the common language of science, and scientific names were in Latin or Greek: Linnaeus continued this practice.
The Geneva Nomenclature of 1892 was created as a result of many other meetings in the past, the first of which was established in 1860 by August Kekulé. Another entity called the International Association of Chemical Societies (IACS) existed, and on 1911, gave vital propositions the new one should address: [ 2 ]
Functional group interconversion can be used in retrosynthetic analysis to plan organic synthesis. A functional group is a group of atoms in a molecule with distinctive chemical properties, regardless of the other atoms in the molecule. The atoms in a functional group are linked to each other and to the rest of the molecule by covalent bonds.
In taxonomy, binomial nomenclature ("two-term naming system"), also called binary nomenclature, is a formal system of naming species of living things by giving each a name composed of two parts, both of which use Latin grammatical forms, although they can be based on words from other languages.
In chemical nomenclature, a descriptor is a notational prefix placed before the systematic substance name, which describes the configuration or the stereochemistry of the molecule. [1] Some of the listed descriptors should not be used in publications , as they no longer accurately correspond with the recommendations of the IUPAC .