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The similarity-based [4] virtual screening (a kind of ligand-based virtual screening) assumes that all compounds in a database that are similar to a query compound have similar biological activity. Although this hypothesis is not always valid, [ 5 ] quite often the set of retrieved compounds is considerably enriched with actives. [ 6 ]
It is a graphical plot of nE° = −ΔG°/F as a function of the oxidation number for the different redox species of a given element. The Gibbs free energy Δ G ° is related to the reduction potential E ° by the formula: Δ G ° = − nFE ° or nE ° = −Δ G °/ F , where n is the number of transferred electrons, and F is the Faraday ...
Li is the only group 1 element which forms a stable nitride, Li 3 N. [4] Mg, as well as other group 2 elements, also form nitrides. [4] Lithium carbonate, phosphate and fluoride are sparingly soluble in water. The corresponding group 2 salts are insoluble. (Think lattice and solvation energies). Both Li and Mg form covalent organometallic compounds
Elements in the same group tend to show similar chemical characteristics. Vertical, horizontal and diagonal trends characterize the periodic table. Metallic character increases going down a group and from right to left across a period. Nonmetallic character increases going from the bottom left of the periodic table to the top right.
The ΔH° form undergoes discontinuities at a phase transition temperatures of the constituent element(s) and the compound. The enthalpy change for any standard reaction is designated ΔH° rx. Standard molar heat of formation of ZnBr 2 (c,l) from the elements, showing discontinuities at transition temperatures of the elements and the compound.
A homologue (also spelled as homolog) is a compound belonging to a homologous series. [1] Compounds within a homologous series typically have a fixed set of functional groups that gives them similar chemical and physical properties. (For example, the series of primary straight-chained alcohols has a hydroxyl at the end of the carbon chain ...
Atomicity is the total number of atoms present in a molecule of an element. For example, each molecule of oxygen (O 2) is composed of two oxygen atoms. Therefore, the atomicity of oxygen is 2. [1] In older contexts, atomicity is sometimes equivalent to valency. Some authors also use the term to refer to the maximum number of valencies observed ...
The law of definite proportion was given by Joseph Proust in 1797. [2]I shall conclude by deducing from these experiments the principle I have established at the commencement of this memoir, viz. that iron like many other metals is subject to the law of nature which presides at every true combination, that is to say, that it unites with two constant proportions of oxygen.
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