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In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula −OH and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry , alcohols and carboxylic acids contain one or more hydroxy groups.
A hydroxyl group (OH −) attaches to one carbon of the double bond, and a proton (H +) adds to the other. The reaction is highly exothermic. In the first step, the alkene acts as a nucleophile and attacks the proton, following Markovnikov's rule. In the second step an H 2 O molecule bonds to the other, more highly substituted carbon.
In chemistry, hydroxylation refers to the installation of a hydroxyl group (−OH) into an organic compound. Hydroxylations generate alcohols and phenols, which are very common functional groups. Hydroxylation confers some degree of water-solubility. Hydroxylation of a hydrocarbon is an oxidation, thus a step in degradation.
An ester of a carboxylic acid.R stands for any group (typically hydrogen or organyl) and R ′ stands for any organyl group.. In chemistry, an ester is a compound derived from an acid (organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group (−OH) of that acid is replaced by an organyl group (R ′). [1]
Functional group interconversion can be used in retrosynthetic analysis to plan organic synthesis. A functional group is a group of atoms in a molecule with distinctive chemical properties, regardless of the other atoms in the molecule. The atoms in a functional group are linked to each other and to the rest of the molecule by covalent bonds.
Structure of the hydroxyl (-OH) functional group. The suffix –ol is used in organic chemistry principally to form names of organic compounds containing the hydroxyl (–OH) group, mainly alcohols. The suffix was extracted from the word alcohol. The suffix also appears in some trivial names with reference to oils (from Latin oleum, oil).
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Hydroxyl groups ortho or para to the carbonyl group concentrate electron density at the aryl carbon bonded to the carbonyl carbon (10c, 11d). Phenyl groups have low migratory aptitude, but higher electron density at the migrating carbon increases migratory aptitude, facilitating [1,2]-aryl migration and allowing the reaction to continue.