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In the process of passing through a cycle, the working fluid (system) may convert heat from a warm source into useful work, and dispose of the remaining heat to a cold sink, thereby acting as a heat engine. Conversely, the cycle may be reversed and use work to move heat from a cold source and transfer it to a warm sink thereby acting as a heat ...
It also contrasts with idealized frictionless processes in the surroundings, which may be thought of as including 'purely mechanical systems'; this difference comes close to defining a thermodynamic process. [1] (2) A cyclic process carries the system through a cycle of stages, starting and being completed in some particular state. The ...
In chemistry, thermochemical cycles combine solely heat sources (thermo) with chemical reactions to split water into its hydrogen and oxygen components. [1] The term cycle is used because aside of water, hydrogen and oxygen, the chemical compounds used in these processes are continuously recycled.
The other way referred to an incremental change in the internal state of the system, and did not expect the process to be cyclic. A cyclic process is one that can be repeated indefinitely often, returning the system to its initial state. Of particular interest for single cycle of a cyclic process are the net work done, and the net heat taken in ...
Every introductory thermodynamics text [15] [16] presents the fact that on such a plane the area under any curve is the heat transfer to the substance per mole, positive going from left to right and negative from right to left; moreover, in a cyclic process the net heat transfer to the substance is the area enclosed by the cycle's closed curve.
A Carnot cycle is an ideal thermodynamic cycle proposed by French physicist Sadi Carnot in 1824 and expanded upon by others in the 1830s and 1840s. By Carnot's theorem, it provides an upper limit on the efficiency of any classical thermodynamic engine during the conversion of heat into work, or conversely, the efficiency of a refrigeration system in creating a temperature difference through ...
The lattice enthalpy is the enthalpy change involved in the formation of an ionic compound from gaseous ions (an exothermic process), or sometimes defined as the energy to break the ionic compound into gaseous ions (an endothermic process). A Born–Haber cycle applies Hess's law to calculate the lattice enthalpy by comparing the standard ...
The cycle is reversible, meaning that if supplied with mechanical power, it can function as a heat pump for heating or cooling, and even for cryogenic cooling. The cycle is defined as a closed regenerative cycle with a gaseous working fluid. "Closed cycle" means the working fluid is permanently contained within the thermodynamic system.