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  2. Half-reaction - Wikipedia

    en.wikipedia.org/wiki/Half-reaction

    For oxidation-reduction reactions in acidic conditions, after balancing the atoms and oxidation numbers, one will need to add H + ions to balance the hydrogen ions in the half reaction. For oxidation-reduction reactions in basic conditions, after balancing the atoms and oxidation numbers, first treat it as an acidic solution and then add OH − ...

  3. Linear sweep voltammetry - Wikipedia

    en.wikipedia.org/wiki/Linear_sweep_voltammetry

    E s is the reduction potential of A (if the electrolyte and the electrode are in their standard conditions, then this potential is a standard reduction potential). As E approaches E s, the current on the surface increases, and when E = E s, the concentration of A equals that of the oxidized/reduced A at the surface ([A] = [A −]). [4]

  4. Latimer diagram - Wikipedia

    en.wikipedia.org/wiki/Latimer_diagram

    Since Δ r G o = -nFE o, the electrode potential is a representation of the Gibbs energy change for the given reduction. The sum of the Gibbs energy changes for subsequent reductions (e.g. from O 2 to H 2 O 2, then from H 2 O 2 to H 2 O) is the same as the Gibbs energy change for the overall reduction (i.e. from O 2 to H 2 O), in accordance ...

  5. Redox - Wikipedia

    en.wikipedia.org/wiki/Redox

    Redox (/ ˈ r ɛ d ɒ k s / RED-oks, / ˈ r iː d ɒ k s / REE-doks, reductionoxidation [2] or oxidationreduction [3]: 150 ) is a type of chemical reaction in which the oxidation states of the reactants change. [4] Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...

  6. Standard electrode potential - Wikipedia

    en.wikipedia.org/wiki/Standard_electrode_potential

    Bipolar electrochemistry scheme. In electrochemistry, standard electrode potential, or , is a measure of the reducing power of any element or compound.The IUPAC "Gold Book" defines it as; "the value of the standard emf (electromotive force) of a cell in which molecular hydrogen under standard pressure is oxidized to solvated protons at the left-hand electrode".

  7. Reducing agent - Wikipedia

    en.wikipedia.org/wiki/Reducing_agent

    For oxygen (O) the oxidation number began as 0 and decreased to 2−. These changes can be viewed as two "half-reactions" that occur concurrently: Oxidation half reaction: Fe 0 → Fe 3+ + 3e −; Reduction half reaction: O 2 + 4e − → 2 O 2−; Iron (Fe) has been oxidized because the oxidation number increased.

  8. Oxidizing agent - Wikipedia

    en.wikipedia.org/wiki/Oxidizing_agent

    The international pictogram for oxidizing chemicals. Dangerous goods label for oxidizing agents. An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or "accepts"/"receives" an electron from a reducing agent (called the reductant, reducer, or electron donor).

  9. Nernst equation - Wikipedia

    en.wikipedia.org/wiki/Nernst_equation

    In electrochemistry, the Nernst equation is a chemical thermodynamical relationship that permits the calculation of the reduction potential of a reaction (half-cell or full cell reaction) from the standard electrode potential, absolute temperature, the number of electrons involved in the redox reaction, and activities (often approximated by concentrations) of the chemical species undergoing ...