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In chemistry, pH (/ p iː ˈ eɪ tʃ / pee-AYCH), also referred to as acidity or basicity, historically denotes "potential of hydrogen" (or "power of hydrogen"). [1] It is a logarithmic scale used to specify the acidity or basicity of aqueous solutions.
The Hammett acidity function (H 0) is a measure of acidity that is used for very concentrated solutions of strong acids, including superacids.It was proposed by the physical organic chemist Louis Plack Hammett [1] [2] and is the best-known acidity function used to extend the measure of Brønsted–Lowry acidity beyond the dilute aqueous solutions for which the pH scale is useful.
The concentration of hydrogen ions and pH are inversely proportional; in an aqueous solution, an increased concentration of hydrogen ions yields a low pH, and subsequently, an acidic product. By definition, an acid is an ion or molecule that can donate a proton, and when introduced to a solution it will react with water molecules (H 2 O) to ...
A logarithmic unit is a unit that can be used to express a quantity (physical or mathematical) on a logarithmic scale, that is, as being proportional to the value of a logarithm function applied to the ratio of the quantity and a reference quantity of the same type. The choice of unit generally indicates the type of quantity and the base of the ...
The distribution coefficient, log D, is the ratio of the sum of the concentrations of all forms of the compound (ionized plus un-ionized) in each of the two phases, one essentially always aqueous; as such, it depends on the pH of the aqueous phase, and log D = log P for non-ionizable compounds at any pH.
Published values for log K 1 and log K D are 5.89 and 2.05, respectively. [2] Using these values and the equality conditions, the concentrations of the three species, chromate CrO 2− 4 , hydrogen chromate HCrO − 4 and dichromate Cr 2 O 2− 7 can be calculated, for various values of pH, by means of the equilibrium expressions.
The spectral series of hydrogen, on a logarithmic scale. The emission spectrum of atomic hydrogen has been divided into a number of spectral series, with wavelengths given by the Rydberg formula. These observed spectral lines are due to the electron making transitions between two energy levels in an atom.
C A is the analytical concentration of the acid and C H is the concentration the hydrogen ion that has been added to the solution. The self-dissociation of water is ignored. A quantity in square brackets, [X], represents the concentration of the chemical substance X. It is understood that the symbol H + stands for the hydrated hydronium ion.