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Isotherms of an ideal gas for different temperatures. The curved lines are rectangular hyperbolae of the form y = a/x. They represent the relationship between pressure (on the vertical axis) and volume (on the horizontal axis) for an ideal gas at different temperatures: lines that are farther away from the origin (that is, lines that are nearer to the top right-hand corner of the diagram ...
The ideal gas law is the equation of state for an ideal gas, given by: = where P is the pressure; V is the volume; n is the amount of substance of the gas (in moles) T is the absolute temperature; R is the gas constant, which must be expressed in units consistent with those chosen for pressure, volume and temperature.
The van der Waals equation is a mathematical formula that describes the behavior of real gases.It is an equation of state that relates the pressure, temperature, and molar volume in a fluid.
In physics, the thermal equation of state is a mathematical expression of pressure P, temperature T, and, volume V.The thermal equation of state for ideal gases is the ideal gas law, expressed as PV=nRT (where R is the gas constant and n the amount of substance), while the thermal equation of state for solids is expressed as:
where P is the pressure, V is the volume, N is the number of gas molecules, k B is the Boltzmann constant (1.381×10 −23 J·K −1 in SI units) and T is the absolute temperature. These equations are exact only for an ideal gas, which neglects various intermolecular effects (see real gas). However, the ideal gas law is a good approximation for ...
For an ideal gas the equation of state can be written as =, where R is the ideal gas constant.The differential change of the chemical potential between two states of slightly different pressures but equal temperature (i.e., dT = 0) is given by = = = , where ln p is the natural logarithm of p.
Therefore, the kinetic energy per kelvin of one mole of monatomic ideal gas (D = 3) is = =, where is the Avogadro constant, and R is the ideal gas constant. Thus, the ratio of the kinetic energy to the absolute temperature of an ideal monatomic gas can be calculated easily:
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".