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Carbon-14, C-14, 14 C or radiocarbon, is a radioactive isotope of carbon with an atomic nucleus containing 6 protons and 8 neutrons. Its presence in organic matter is the basis of the radiocarbon dating method pioneered by Willard Libby and colleagues (1949) to date archaeological, geological and hydrogeological samples.
Carbon (6 C) has 14 known isotopes, from 8 C to 20 C as well as 22 C, of which 12 C and 13 C are stable. The longest-lived radioisotope is 14 C, with a half-life of 5.70(3) × 10 3 years. This is also the only carbon radioisotope found in nature, as trace quantities are formed cosmogenically by the reaction 14 N + n → 14 C + 1 H. The most ...
Carbon-14 is formed in upper layers of the troposphere and the stratosphere at altitudes of 9–15 km by a reaction that is precipitated by cosmic rays. [66] Thermal neutrons are produced that collide with the nuclei of nitrogen-14, forming carbon-14 and a proton. As such, 1.5% × 10 −10 of atmospheric carbon dioxide contains carbon-14. [67]
The number of nucleons (both protons and neutrons) in the nucleus is the atom's mass number, and each isotope of a given element has a different mass number. For example, carbon-12, carbon-13, and carbon-14 are three isotopes of the element carbon with mass numbers 12, 13, and 14, respectively. The atomic number of carbon is 6, which means that ...
Examples include carbon-14, nitrogen-15, and oxygen-16 in the table above. Isobars are nuclides with the same number of nucleons (i.e. mass number) but different numbers of protons and neutrons. Isobars neighbor each other diagonally from lower-left to upper-right. Examples include carbon-14, nitrogen-14, and oxygen-14 in the table above.
Deuterium, 2 H (atomic mass 2.014 101 777 844 (15) Da), the other stable hydrogen isotope, has one proton and one neutron in its nucleus, called a deuteron. 2 H comprises 26–184 ppm (by population, not mass) of hydrogen on Earth; the lower number tends to be found in hydrogen gas and higher enrichment (150 ppm) is typical of seawater.
For other isotopes, the isotopic mass is usually within 0.1 u of the mass number. For example, 35 Cl (17 protons and 18 neutrons) has a mass number of 35 and an isotopic mass of 34.96885. [7] The difference of the actual isotopic mass minus the mass number of an atom is known as the mass excess, [8] which for 35 Cl is –0.03115.
The neutron number (symbol N) is the number of neutrons in a nuclide. Atomic number (proton number) plus neutron number equals mass number : Z + N = A . The difference between the neutron number and the atomic number is known as the neutron excess: D = N − Z = A − 2 Z .