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Moreover, 239 Pu and 240 Pu cannot be chemically distinguished, so expensive and difficult isotope separation would be necessary to separate them. Weapons-grade plutonium is defined as containing no more than 7% 240 Pu; this is achieved by only exposing 238 U to neutron sources for short periods of time to minimize the 240 Pu produced.
Pu-239 is produced artificially in nuclear reactors when a neutron is absorbed by U-238, forming U-239, which then decays in a rapid two-step process into Pu-239. [22] It can then be separated from the uranium in a nuclear reprocessing plant. [23] Weapons-grade plutonium is defined as being predominantly Pu-239, typically about 93% Pu-239. [24]
239 Pu is virtually nonexistent in nature. It is made by bombarding uranium-238 with neutrons. Uranium-238 is present in quantity in most reactor fuel; hence 239 Pu is continuously made in these reactors. Since 239 Pu can itself be split by neutrons to release energy, 239 Pu provides a portion of the energy generation in a nuclear reactor.
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The first production reactor that made 239 Pu was the X-10 Graphite Reactor. It went online in 1943 and was built at a facility in Oak Ridge that later became the Oak Ridge National Laboratory. [42] [note 5] In January 1944, workers laid the foundations for the first chemical separation building, T Plant located in 200-West.
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In contrast, the generic civilian Pressurized water reactor, routinely does (typical for 2015 Generation II reactor) 45 GWd/tU of burnup, resulting in the purity of Pu-239 being 50.5%, alongside a Pu-240 content of 25.2%, [5] [6] The remaining portion includes much more of the heat generating Pu-238 and Pu-241 isotopes than are to be found in ...
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