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A 3 He/ 4 He dilution refrigerator is a cryogenic device that provides continuous cooling to temperatures as low as 2 mK, with no moving parts in the low-temperature region. [1] [2] The cooling power is provided by the heat of mixing of the helium-3 and helium-4 isotopes.
Here, R A is the isotope amount ratio of the natural analyte, R A = n(i A) A /n(j A) A, R B is the isotope amount ratio of the isotopically enriched analyte, R B = n(i A) B /n(j A) B, R AB is the isotope amount ratio of the resulting mixture, x(j A) A is the isotopic abundance of the minor isotope in the natural analyte, and x(j A) B is the ...
Stable isotopes partitioning between two substances A and B can be expressed by the use of the isotopic fractionation factor (alpha): α A-B = R A /R B. where R is the ratio of the heavy to light isotope (e.g., 2 H/ 1 H or 18 O/ 16 O). Values for alpha tend to be very close to 1. [1] [2]
The amount of liquid-vapor equilibrium fractionation for hydrogen isotopes is about 8x that of oxygen isotopes at Earth surface temperatures, which reflects the relative mass differences of the two isotope systems: 2 H is 100% heavier than 1 H, 18 O is 12.5% heavier than 16 O. Above the boundary layer, there is a transition zone with relative ...
Equilibrium isotope fractionation is the partial separation of isotopes between two or more substances in chemical equilibrium. Equilibrium fractionation is strongest at low temperatures, and (along with kinetic isotope effects) forms the basis of the most widely used isotopic paleothermometers (or climate proxies): D/H and 18 O/ 16 O records from ice cores, and 18 O/ 16 O records from calcium ...
Archaeological materials, such as bone, organic residues, hair, or sea shells, can serve as substrates for isotopic analysis. Carbon, nitrogen and zinc isotope ratios are used to investigate the diets of past people; these isotopic systems can be used with others, such as strontium or oxygen, to answer questions about population movements and cultural interactions, such as trade.
An example is water, whose hydrogen-related isotopologues are: "light water" (HOH or H 2 O), "semi-heavy water" with the deuterium isotope in equal proportion to protium (HDO or 1 H 2 HO), "heavy water" with two deuterium atoms (D 2 O or 2 H 2 O); and "super-heavy water" or tritiated water (T 2 O or 3 H 2 O, as well as HTO [1 H 3 HO] and DTO [2 ...
Separative work unit (SWU) is a complex unit which is a function of the amount of uranium processed and the degree to which it is enriched, i.e. the extent of increase in the concentration of the U-235 isotope relative to the remainder. The unit is strictly: kilogram separative work unit, and it measures the quantity of separative work ...