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The smaller the difference, the more the overlap. The case of citric acid is shown at the right; solutions of citric acid are buffered over the whole range of pH 2.5 to 7.5. According to Pauling's first rule, successive pK values of a given acid increase (pK a2 > pK a1). [28]
The Charlot equation, named after Gaston Charlot, is used in analytical chemistry to relate the hydrogen ion concentration, and therefore the pH, with the formal analytical concentration of an acid and its conjugate base. It can be used for computing the pH of buffer solutions when the approximations of the Henderson–Hasselbalch equation ...
In chemistry, biochemistry, and pharmacology, a dissociation constant (K D) is a specific type of equilibrium constant that measures the propensity of a larger object to separate (dissociate) reversibly into smaller components, as when a complex falls apart into its component molecules, or when a salt splits up into its component ions.
The hydroxyl value can be calculated using the following equation. Note that a chemical substance may also have a measurable acid value affecting the measured endpoint of the titration. The acid value ( AV ) of the substance, determined in a separate experiment, enters into this equation as a correction factor in the calculation of the hydroxyl ...
In such cases, the system can be treated as a mixture of the acid or base and water, which is an amphoteric substance. By accounting for the self-ionization of water, the true pH of the solution can be calculated. For example, a 5 × 10 −8 M solution of HCl would have a pH of 6.89 when treated as a mixture of HCl and water. The self ...
Acetic acid is said to be a differentiating solvent for the three acids, while water is not. [6]: (p. 217) An important example of a solvent which is more basic than water is dimethyl sulfoxide, DMSO, (). A compound which is a weak acid in water may become a strong acid in DMSO.
K ow, being a type of partition coefficient, serves as a measure of the relationship between lipophilicity (fat solubility) and hydrophilicity (water solubility) of a substance. The value is greater than one if a substance is more soluble in fat-like solvents such as n-octanol, and less than one if it is more soluble in water. [citation needed]
Helicity is a pseudo-scalar quantity: it changes sign under change from a right-handed to a left-handed frame of reference; it can be considered as a measure of the handedness (or chirality) of the flow. Helicity is one of the four known integral invariants of the Euler equations; the other three are energy, momentum and angular momentum.