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A less common, but very severe, form of ESA is the thaumasitic form of sulfate attack (TSA) when concrete is exposed to an external source of sulfate in the concomitant presence of carbonate, HCO − 3 ions, or CO 2. [24] It preferentially occurs in clay formations exposed to air oxygen by excavation works and in which pyrite has been oxidized.
Siliceous organisms in the ocean, such as diatoms and radiolaria, are the primary sink of dissolved silicic acid into opal silica. [32] Only 3% of the Si molecules dissolved in the ocean are exported and permanently deposited in marine sediments on the seafloor each year, demonstrating that silicon recycling is a dominant process in the oceans ...
Tufa columns at Mono Lake, California. Tufa is a variety of limestone formed when carbonate minerals precipitate out of water in unheated rivers or lakes. Geothermally heated hot springs sometimes produce similar (but less porous) carbonate deposits, which are known as travertine or thermogene travertine.
This figure describes the geological aspects and processes of the carbonate silicate cycle, within the long-term carbon cycle. The carbonate–silicate geochemical cycle, also known as the inorganic carbon cycle, describes the long-term transformation of silicate rocks to carbonate rocks by weathering and sedimentation, and the transformation of carbonate rocks back into silicate rocks by ...
Silicic acid (H 4 SiO 4) in the silica-enriched fluids forms lenticular, nodular, fibrous, or aggregated quartz, opal, or chalcedony that grows within the rock. [5] Silicification happens when rocks or organic materials are in contact with silica-rich surface water, buried under sediments and susceptible to groundwater flow, or buried under ...
Carbonatation is a slow process that occurs in concrete where lime (CaO, or Ca(OH) 2 ) in the cement reacts with carbon dioxide (CO 2) from the air and forms calcium carbonate. The water in the pores of Portland cement concrete is normally alkaline with a pH in the range of 12.5 to 13.5.
Natural pozzolana (volcanic ash) deposits situated in Southern California in the United States. Pozzolans are a broad class of siliceous and aluminous materials which, in themselves, possess little or no cementitious value but which will, in finely divided form and in the presence of water, react chemically with calcium hydroxide (Ca(OH) 2) at ordinary temperature to form compounds possessing ...
A prompt reaction initiated at the early stage of concrete hardening on very fine silica particles will help to suppress a slow and delayed reaction with larger siliceous aggregates on the long term. Following the same principle, the fabrication of low-pH cement also implies the addition of finely divided pozzolanic materials rich in silicic ...