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The all-cis isomer , a fully convex decagon, would have bond angles of 144°, which creates large amounts of angle strain relative to the ideal 120° in sp 2 atomic hybridization. Instead, the all- cis isomer adopts a planar boat-like conformation ( 2 ) to relieve the angle strain, [ 5 ] although it, too, is less stable than the next planar ...
Cyclododecatrienes are cyclic trienes with the formula C 12 H 18.Four isomers are known for 1,5,9-cyclododecatriene. The trans,trans,cis-isomer is a precursor in the production of nylon-12.
Decene / d ɛ k iː n / is an organic compound with the chemical formula C 10 H 20. Decene contains a chain of ten carbon atoms with one double bond, making it an alkene. There are many isomers of decene depending on the position and geometry of the double bond. Dec-1-ene is the only isomer of industrial importance.
Cyclodecene is a cycloalkene with a ten-membered ring, with two possible geometric isomers, denoted cis-cyclodecene and trans-cyclodecene, or (Z)-cyclodecene and (E)-cyclodecene. References [ edit ]
The cis isomer in this case has a boiling point of 60.3 °C, while the trans isomer has a boiling point of 47.5 °C. [6] In the cis isomer the two polar C–Cl bond dipole moments combine to give an overall molecular dipole, so that there are intermolecular dipole–dipole forces (or Keesom forces), which add to the London dispersion forces and ...
The descriptors cis (Latin, on this side of) [2] and trans (Latin, over, beyond) [3] are used in various contexts for the description of chemical configurations: [4] [5] In organic structural chemistry , the configuration of a double bond can be described with cis and trans , in case it has a simple substitution pattern with only two residues.
Decalin occurs in cis and trans forms.The trans form is energetically more stable because of fewer steric interactions. cis-Decalin is a chiral molecule without a chiral center; it has a two-fold rotational symmetry axis, but no reflective symmetry.
In larger rings (8 or more atoms), cis–trans isomerism of the double bond may occur. This stability pattern forms part of the origin of Bredt's rule , the observation that alkenes do not form at the bridgehead of many types of bridged ring systems because the alkene would necessarily be trans in one of the rings.