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A carbon–oxygen bond is a polar covalent bond between atoms of carbon and oxygen. [1] [2] [3]: 16–22 Carbon–oxygen bonds are found in many inorganic compounds such as carbon oxides and oxohalides, carbonates and metal carbonyls, [4] and in organic compounds such as alcohols, ethers, and carbonyl compounds.
Oxygen is the third most abundant chemical element in the universe, after hydrogen and helium. [68] About 0.9% of the Sun's mass is oxygen. [19] Oxygen constitutes 49.2% of the Earth's crust by mass [69] as part of oxide compounds such as silicon dioxide and is the most abundant element by mass in the Earth's crust.
Oxygen can form oxides with heavier noble gases xenon and radon, although this needs indirect methods. Even though no oxides of krypton are known, oxygen is able to form covalent bonds with krypton in an unstable compound Kr(OTeF 5) 2. One unexpected oxygen compound is dioxygenyl hexafluoroplatinate, O + 2 PtF −
Atomic oxygen, denoted O or O 1, is very reactive, as the individual atoms of oxygen tend to quickly bond with nearby molecules. Its lowest-energy electronic state is a spin triplet, designated by the term symbol 3 P. On Earth's surface, it exists naturally for a very short time.
The polarity of C=O bond also enhances the acidity of any adjacent C-H bonds. Due to the positive charge on carbon and the negative charge on oxygen, carbonyl groups are subject to additions and/or nucleophilic attacks. A variety of nucleophiles attack, breaking the carbon-oxygen double bond, and leading to addition-elimination reactions.
Double bonds occur most commonly between two carbon atoms, for example in alkenes. Many double bonds exist between two different elements: for example, in a carbonyl group between a carbon atom and an oxygen atom. Other common double bonds are found in azo compounds (N=N), imines (C=N), and sulfoxides (S=O).
Under a molecular orbital theory framework, the oxygen-oxygen bond in triplet dioxygen is better described as one full σ bond plus two π half-bonds, each half-bond accounted for by two-center three-electron (2c-3e) bonding, to give a net bond order of two (1+2× 1 / 2 ), while also accounting for the spin state (S = 1).
Chlorine and oxygen can bond in a number of ways: chlorine monoxide radical, ClO•, chlorine (II) oxide radical; chloroperoxyl radical, ClOO•, chlorine (II) peroxide radical; chlorine dioxide, ClO 2, chlorine (IV) oxide; chlorine trioxide radical, ClO 3 •, chlorine (VI) oxide radical; chlorine tetroxide radical, ClO 4 •, chlorine (VII ...