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Stokes–Einstein–Sutherland equation, for diffusion of spherical particles through a liquid with low Reynolds number: = Here q is the electrical charge of a particle; μ q is the electrical mobility of the charged particle; η is the dynamic viscosity;
Stokes' law is important for understanding the swimming of microorganisms and sperm; also, the sedimentation of small particles and organisms in water, under the force of gravity. [ 5 ] In air, the same theory can be used to explain why small water droplets (or ice crystals) can remain suspended in air (as clouds) until they grow to a critical ...
For instance, a 20% saline (sodium chloride) solution has viscosity over 1.5 times that of pure water, whereas a 20% potassium iodide solution has viscosity about 0.91 times that of pure water. An idealized model of dilute electrolytic solutions leads to the following prediction for the viscosity μ s {\displaystyle \mu _{s}} of a solution: [ 57 ]
The Stokes-Einstein equation describes a frictional force on a sphere of diameter as = where is the viscosity of the solution. Inserting this into 9 gives an estimate for k D {\displaystyle k_{D}} as 8 R T 3 η {\displaystyle {\frac {8RT}{3\eta }}} , where R is the gas constant, and η {\displaystyle \eta } is given in centipoise.
At first, the predictions of Einstein's formula were seemingly refuted by a series of experiments by Svedberg in 1906 and 1907, which gave displacements of the particles as 4 to 6 times the predicted value, and by Henri in 1908 who found displacements 3 times greater than Einstein's formula predicted. [19]
The Einstein field equations (EFE) may be written in the form: [5] [1] + = EFE on a wall in Leiden, Netherlands. where is the Einstein tensor, is the metric tensor, is the stress–energy tensor, is the cosmological constant and is the Einstein gravitational constant.
A smaller ion with stronger hydration, for example, may have a greater Stokes radius than a larger ion with weaker hydration. This is because the smaller ion drags a greater number of water molecules with it as it moves through the solution. [1] Stokes radius is sometimes used synonymously with effective hydrated radius in solution. [2]
The three viscosity equations now coalesce to a single viscosity equation = = because a nondimensional scaling is used for the entire viscosity equation. The standard nondimensionality reasoning goes like this: Creating nondimensional variables (with subscript D) by scaling gives