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Miscibility (/ ˌ m ɪ s ɪ ˈ b ɪ l ɪ t i /) is the property of two substances to mix in all proportions (that is, to fully dissolve in each other at any concentration), forming a homogeneous mixture (a solution). Such substances are said to be miscible (etymologically equivalent to the common term "mixable").
The word upper indicates that the UCST is an upper bound to a temperature range of partial miscibility, or miscibility for certain compositions only. For example, hexane-nitrobenzene mixtures have a UCST of 19 °C (66 °F), so that these two substances are miscible in all proportions above 19 °C (66 °F) but not at lower temperatures.
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For example, the system triethylamine-water has an LCST of 19 °C, so that these two substances are miscible in all proportions below 19 °C but not at higher temperatures. [ 1 ] [ 2 ] The nicotine -water system has an LCST of 61 °C, and also a UCST of 210 °C at pressures high enough for liquid water to exist at that temperature.
Of course, any notion of "finding" a molecule in a given location is a thought experiment since we can't actually examine spatial locations the size of molecules. The expression for the entropy of mixing of small molecules in terms of mole fractions is no longer reasonable when the solute is a macromolecular chain .
In chemistry, the lever rule is a formula used to determine the mole fraction (x i) or the mass fraction (w i) of each phase of a binary equilibrium phase diagram.It can be used to determine the fraction of liquid and solid phases for a given binary composition and temperature that is between the liquidus and solidus line.
A miscibility gap between isostructural phases may be described as the solvus, a term also used to describe the boundary on a phase diagram between a miscibility gap and other phases. [2] Thermodynamically, miscibility gaps indicate a maximum (e.g. of Gibbs energy) in the composition range. [3] [4]
Thomson's experiments with cathode rays (1897): J. J. Thomson's cathode ray tube experiments (discovers the electron and its negative charge). Eötvös experiment (1909): Loránd Eötvös publishes the result of the second series of experiments, clearly demonstrating that inertial and gravitational mass are one and the same.