Search results
Results from the WOW.Com Content Network
In the decade that ensued, selenium-mediated oxidation rapidly expanded in use, and in 1939, Andre Guillemonat and co-workers disclosed the selenium dioxide-mediated oxidation of olefins at the allylic position. [2] Today, selenium-dioxide-mediated oxidation of methylene groups to alpha ketones and at the allylic position of olefins is known as ...
The selenium starting material is reduced to selenium, and precipitates as a red amorphous solid which can easily be filtered off. [10] This type of reaction is called a Riley oxidation. It is also renowned as a reagent for allylic oxidation, [11] a reaction that entails the following conversion Allylic oxidation. This can be described more ...
Selenium dioxide oxidation In terms of reaction mechanism , SeO 2 and the allylic substrate react via pericyclic process beginning with an ene reaction that activates the C−H bond. The second step is a [2,3] sigmatropic reaction .
The conversion of valencene to nootkatone is an example of allylic oxidation. In the synthesis of some fine chemicals, selenium dioxide is used to convert alkenes to allylic alcohols: [15] R 2 C=CR'-CHR" 2 + [O] → R 2 C=CR'-C(OH)R" 2. where R, R', R" may be alkyl or aryl substituents.
Selenium disulfide has been used in shampoo as an antidandruff agent, an inhibitor in polymer chemistry, a glass dye, and a reducing agent in fireworks. [6] Selenium trioxide may be synthesized by dehydrating selenic acid, H 2 SeO 4, which is itself produced by the oxidation of selenium dioxide with hydrogen peroxide: [8]
Allyl alcohols in general are prepared by allylic oxidation of allyl compounds, using selenium dioxide or organic peroxides. Other methods include carbon-carbon bond-forming reactions such as the Prins reaction, the Morita-Baylis-Hillman reaction, or a variant of the Ramberg-Bäcklund reaction. Hydrogenation of enones is another route.
The U.S. Food and Drug Administration (FDA) now classifies eggs as a “healthy, nutrient-dense" food, according to a new proposed rule. Registered dietitians react to the change.
Riley remained at Imperial College as a demonstrator and later lecturer from 1923 to 1932, where he continued to pursue research in inorganic chemistry.He began to study the role of selenium oxides as oxidants of organic compounds, pioneering a new chemical process involving Selenium, known today as Riley oxidation.