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Precipitated silica is an amorphous form of silica (silicon dioxide, SiO 2); it is a white, powdery material. Precipitated silica is produced by precipitation from a solution containing silicate salts. The three main classes of amorphous silica are pyrogenic silica, precipitated silica and silica gel.
Sodium silicates are stable in neutral and alkaline solutions. In acidic solutions, the silicate ions react with hydrogen ions to form silicic acids, which tend to decompose into hydrated silicon dioxide gel. [citation needed] Heated to drive off the water, the result is a hard translucent substance called silica gel, widely used as a desiccant ...
They form several solid hydrates when crystallized from solution. Soluble sodium silicates and mixtures thereof, known as waterglass are important industrial and household chemicals. Silicates of non-alkali cations, or with sheet and tridimensional polymeric anions, generally have negligible solubility in water at normal conditions.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
These products are often called precipitated silica or silica sols. Hydrogen ions from the surface of colloidal silica tend to dissociate in aqueous solution, yielding a high negative charge. Substitution of some of the Si atoms by Al is known increase the negative colloidal charge, especially when it is evaluated at pH below the neutral point ...
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
The solubility of silica strongly depends on the temperature and pH value of the environment [3] where pH9 is the controlling value. [1] Under a condition of pH lower than 9, silica precipitates out of the fluid; when the pH value is above 9, silica becomes highly soluble. [3]
[4] [5] [6] Dehydrating the latter yields a hard translucent form of silica with atomic-scale pores, called silica gel, which is widely used as water absorbent and drying agent. Silica dissolves very sparingly in water [citation needed] and is present in seawater at concentrations below 100 parts per million. In such dilute solutions, silica is ...