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The hydride reacts with the weak Bronsted acid releasing H 2. Hydrides such as calcium hydride are used as desiccants, i.e. drying agents, to remove trace water from organic solvents. The hydride reacts with water forming hydrogen and hydroxide salt. The dry solvent can then be distilled or vacuum transferred from the "solvent pot".
The beta cells of the pancreas in type 1 diabetes produce an excess of the gas, leading to the death of these cells and to a reduced production of insulin by those that remain. [5] In 2005, it was shown that mice can be put into a state of suspended animation-like hypothermia by applying a low dosage of hydrogen sulfide (81 ppm H 2 S) in the air.
A nickel–hydrogen battery (NiH 2 or Ni–H 2) is a rechargeable electrochemical power source based on nickel and hydrogen. [5] It differs from a nickel–metal hydride (NiMH) battery by the use of hydrogen in gaseous form, stored in a pressurized cell at up to 1200 psi (82.7 bar) pressure. [6]
In this diagram, the hydride acceptor C4 carbon is shown at the top. When the nicotinamide ring lies in the plane of the page with the carboxy-amide to the right, as shown, the hydride donor lies either "above" or "below" the plane of the page. If "above" hydride transfer is class A, if "below" hydride transfer is class B. [56]
FAD is the more complex and abundant form of flavin and is reported to bind to 75% of the total flavoproteome [16] and 84% of human encoded flavoproteins. [17] Cellular concentrations of free or non-covalently bound flavins in a variety of cultured mammalian cell lines were reported for FAD (2.2-17.0 amol/cell) and FMN (0.46-3.4 amol/cell). [18]
Usually hydride refers to hydrogen in a compound with a more electropositive element. For hydrides other than group 1 and 2 metals, the term can be misleading, considering the low electronegativity of hydrogen. A well known hydride is lithium aluminium hydride, the [AlH 4] − anion carries hydridic centers firmly attached to the Al(III). [90]
Nickel hydride with increased hydrogen content can be made harder and stronger than nickel, but such nickel hydride is also less ductile than nickel. Loss of ductility occurs due to cracks maintaining sharp points due to suppression of elastic deformation by the hydrogen, and voids forming under tension due to decomposition of the hydride. [3]
Hydride is the only anion with no π orbital, so if it is incorporated into a compound, it acts as a π-blocker, reducing dimensionality of the solid. [ 4 ] Oxyhydride structures with heavy metals cannot be properly studied with X-ray diffraction , as hydrogen hardly has any effect on X-rays.