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A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium.
The number and type of phases that will form is hard to predict and is usually determined by experiment. The results of such experiments can be plotted in phase diagrams. The phase diagram shown here is for a single component system. In this simple system, phases that are possible, depend only on pressure and temperature. The markings show ...
Wigner crystal: a crystalline phase of low-density electrons. Hexatic state, a state of matter that is between the solid and the isotropic liquid phases in two dimensional systems of particles. Ferroics; Ferroelastic state, a phenomenon in which a material may exhibit a spontaneous strain.
In thermodynamics, the phase rule is a general principle governing multi-component, multi-phase systems in thermodynamic equilibrium.For a system without chemical reactions, it relates the number of freely varying intensive properties (F) to the number of components (C), the number of phases (P), and number of ways of performing work on the system (N): [1] [2] [3]: 123–125
A typical phase diagram.The solid green line applies to most substances; the dashed green line gives the anomalous behavior of water. In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium. [1]
The figure shows the schematic P-T diagram of a pure substance (as opposed to mixtures, which have additional state variables and richer phase diagrams, discussed below). The commonly known phases solid , liquid and vapor are separated by phase boundaries, i.e. pressure–temperature combinations where two phases can coexist.
The term phase is sometimes used as a synonym for state of matter, but it is possible for a single compound to form different phases that are in the same state of matter. For example, ice is the solid state of water, but there are multiple phases of ice with different crystal structures , which are formed at different pressures and temperatures.
An alternative formulation of the phase diagram for certain ices and other phases of water [13] Ice, water, and water vapour can coexist at the triple point , which is exactly 273.16 K (0.01 °C) at a pressure of 611.657 Pa .