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  2. Elimination reaction - Wikipedia

    en.wikipedia.org/wiki/Elimination_reaction

    Elimination reaction of cyclohexanol to cyclohexene with sulfuric acid and heat [1] An elimination reaction is a type of organic reaction in which two substituents are removed from a molecule in either a one- or two-step mechanism. [2] The one-step mechanism is known as the E2 reaction, and the two-step mechanism is known as the E1 reaction ...

  3. E1cB-elimination reaction - Wikipedia

    en.wikipedia.org/wiki/E1cB-elimination_reaction

    An example of the E1cB reaction mechanism in the degradation of a hemiketal under basic conditions. The E1cB elimination reaction is a type of elimination reaction which occurs under basic conditions, where the hydrogen to be removed is relatively acidic, while the leaving group (such as -OH or -OR) is a relatively poor one. Usually a moderate ...

  4. Evelyn effect - Wikipedia

    en.wikipedia.org/wiki/Evelyn_effect

    An E2 reaction is a One step mechanism in which carbon-hydrogen and carbon-halogen bonds break to form a double bond. C=C Pi bond. An E1 reaction is the Ionization of the carbon-halogen bond breaking to give a carbocation intermediate, then the Deprotonation of the carbocation. For these two reactions, there are 3 possible products, 3-methyl ...

  5. Hammond's postulate - Wikipedia

    en.wikipedia.org/wiki/Hammond's_postulate

    An E1 reaction consists of a unimolecular elimination, where the rate determining step of the mechanism depends on the removal of a single molecular species. This is a two-step mechanism. The more stable the carbocation intermediate is, the faster the reaction will proceed, favoring the products.

  6. Stereoselectivity - Wikipedia

    en.wikipedia.org/wiki/Stereoselectivity

    Stereoconvergence can be considered an opposite of stereospecificity, when the reaction of two different stereoisomers yield a single product stereoisomer. The quality of stereoselectivity is concerned solely with the products, and their stereochemistry. Of a number of possible stereoisomeric products, the reaction selects one or two to be formed.

  7. SN1 reaction - Wikipedia

    en.wikipedia.org/wiki/SN1_reaction

    The reaction involves a carbocation intermediate and is commonly seen in reactions of secondary or tertiary alkyl halides under strongly basic conditions or, under strongly acidic conditions, with secondary or tertiary alcohols. With primary and secondary alkyl halides, the alternative S N 2 reaction occurs.

  8. Labrador Retriever Puppies' First Time in Snow Is Full of ...

    www.aol.com/labrador-retriever-puppies-first...

    It was a winter wonderland outside that day. No wonder the dogs were so excited. The Labrador Retrievers bolted out of the house and into the fluff in the clip.We can just imagine that they were ...

  9. Ubiquitin-activating enzyme - Wikipedia

    en.wikipedia.org/wiki/Ubiquitin-activating_enzyme

    Ubiquitin-activating enzymes, also known as E1 enzymes, catalyze the first step in the ubiquitination reaction, which (among other things) can target a protein for degradation via a proteasome. This covalent bond of ubiquitin or ubiquitin-like proteins to targeted proteins is a major mechanism for regulating protein function in eukaryotic ...