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The (R) configuration is assigned to the stereocenter if the direction of rotation is directed to the right. If one molecule contains several stereocenters, a locant must be placed before the descriptor (for example, in (1 R , 2 S )-2-amino-1-phenylpropan-1-ol, the systematic designation of norephedrine ).
Examples of absolute configuration of some carbohydrates and amino acids according to Fischer projection (D/L system) and Cahn–Ingold–Prelog priority rules (R/S system) The R/S system is an important nomenclature system for denoting enantiomers. This approach labels each chiral center R or S according to a system by which its substituents ...
More generally, for any pair of enantiomers, all of the descriptors are opposite: (R,R) and (S,S) are enantiomers, as are (R,S) and (S,R). Diastereomers have at least one descriptor in common; for example (R,S) and (R,R) are diastereomers, as are (S,R) and (S,S). This holds true also for compounds having more than two stereocenters: if two ...
Cyclohexane is the most stable of the cycloalkanes, due to the stability of adapting to its chair conformer. [4] This conformer stability allows cyclohexane to be used as a standard in lab analyses. More specifically, cyclohexane is used as a standard for pharmaceutical reference in solvent analysis of pharmaceutical compounds and raw materials.
Cyclohexane conformations, including with chair and boat conformations among others. Cycloalkane conformations, including medium rings and macrocycles; Carbohydrate conformation, which includes cyclohexane conformations as well as other details. Allylic strain – energetics related to rotation about the single bond between an sp 2 carbon and ...
For 4-methylcyclohexene, the (S)-configuration leads to two different products: the bromines can add at the axial positions, giving the orientation (1S,3R,4R), or at the equatorial positions, giving the orientation (1S,3S,4S). Similarly, the (R)-configuration produces two different products: axial addition yields the configuration (1R,3S,4S ...
Cyclohexane is a colourless, flammable liquid with a distinctive detergent-like odor, reminiscent of cleaning products (in which it is sometimes used). Cyclohexane is mainly used for the industrial production of adipic acid and caprolactam, which are precursors to nylon. [5] Cyclohexyl (C 6 H 11) is the alkyl substituent of cyclohexane and is ...
A given stereocenter has two possible configurations (R and S), which give rise to stereoisomers (diastereomers and enantiomers) in molecules with one or more stereocenter. For a chiral molecule with one or more stereocenter, the enantiomer corresponds to the stereoisomer in which every stereocenter has the opposite configuration.