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2-Naphthalenethiol is an organosulfur compound with the formula C 10 H 7 SH. It is a white solid. It is a white solid. It is one of two mono thiols of naphthalene , the other being 1-naphthalenethiol .
Traditionally, 2-naphthol is produced by a two-step process that begins with the sulfonation of naphthalene in sulfuric acid: [2] C 10 H 8 + H 2 SO 4 → C 10 H 7 SO 3 H + H 2 O. The sulfonic acid group is then cleaved in molten sodium hydroxide: C 10 H 7 (SO 3 H) + 3 NaOH → C 10 H 7 ONa + Na 2 SO 3 + 2 H 2 O. Neutralization of the product ...
2-Naphthalenethiol This page was last edited on 13 November 2022, at 22:54 (UTC). Text is available under the Creative Commons Attribution-ShareAlike 4.0 License ...
This page was last edited on 8 November 2022, at 18:36 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may apply.
[1] 1-Naphthalenethiol can also be prepared from 1-bromonaphthalene by Pd-catalyzed reaction with the silylthiolate i Pr 3 SiSK followed by hydrolysis of the silathioether. [2] It was first prepared from the Grignard reagent generated from 1-bromonaphthalene. Treatment of that reagent with elemental sulfur followed by acidification gave the ...
This page was last edited on 8 November 2022, at 19:45 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may apply.
Naphthalene-1-sulfonic acid is an organic compound with the formula C 10 H 7 SO 3 H. A colorless, water-soluble solid, it is often available as the dihydrate C 10 H 7 SO 3 H. 2H 2 O. It is one of two monosulfonic acids of naphthalene, the other being the more stable naphthalene-2-sulfonic acid.
Sulfonyl groups can be written as having the general formula R−S(=O) 2 −R′, where there are two double bonds between the sulfur and oxygen. [1]: 53 [2] Sulfonyl groups can be reduced to the sulfide with diisobutylaluminium hydride (DIBALH). Lithium aluminium hydride (LiAlH 4) reduces some but not all sulfones to sulfides. [1]: 1851