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Oxygen (chemical symbol O) has three naturally occurring isotopes: 16 O, 17 O, and 18 O, where the 16, 17 and 18 refer to the atomic mass.The most abundant is 16 O, with a small percentage of 18 O and an even smaller percentage of 17 O. Oxygen isotope analysis considers only the ratio of 18 O to 16 O present in a sample.
In geochemistry, paleoclimatology and paleoceanography δ 18 O or delta-O-18 is a measure of the deviation in ratio of stable isotopes oxygen-18 (18 O) and oxygen-16 (16 O). It is commonly used as a measure of the temperature of precipitation, as a measure of groundwater/mineral interactions, and as an indicator of processes that show isotopic fractionation, like methanogenesis.
O, samples enriched with the other stable isotopes can be used for isotope labeling. For example, it was proven that the oxygen released in photosynthesis originates in H 2 O, rather than in the also consumed CO 2, by isotope tracing experiments. The oxygen contained in CO 2 in turn is used to make up the sugars formed by photosynthesis.
Isotope fractionation occurs during a phase transition, when the ratio of light to heavy isotopes in the involved molecules changes. When water vapor condenses (an equilibrium fractionation), the heavier water isotopes (18 O and 2 H) become enriched in the liquid phase while the lighter isotopes (16 O and 1 H) tend toward the vapor phase. [1]
Paleoclimatologists measure the ratio of oxygen-18 and oxygen-16 in the shells and skeletons of marine organisms to determine the climate millions of years ago (see oxygen isotope ratio cycle). Seawater molecules that contain the lighter isotope , oxygen-16, evaporate at a slightly faster rate than water molecules containing the 12% heavier ...
In ice cores, mainly Arctic and Antarctic, the ratio of 18 O to 16 O (known as δ 18 O) can be used to determine the temperature of precipitation through time.Assuming that atmospheric circulation and elevation has not changed significantly over the poles, the temperature of ice formation can be calculated as equilibrium fractionation between phases of water that is known for different ...
The ratio of the oxygen isotopes oxygen-16 and oxygen-18 incorporated into the calcium carbonate varies with temperature and the oxygen isotopic composition of the water. This oxygen remains "fixed" in the calcium carbonate when the foraminifera dies, falls to the sea bed, and its shell becomes part of the sediment.
5-million-year history, representing the Lisiecki and Raymo (2005) LR04 Benthic Stack Sections of sedimentary cores from off Greenland. Marine isotope stages (MIS), marine oxygen-isotope stages, or oxygen isotope stages (OIS), are alternating warm and cool periods in the Earth's paleoclimate, deduced from oxygen isotope data derived from deep sea core samples.