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It may refer more specifically to the following manganese minerals: Birnessite, (Na,Ca) 0.5 (Mn IV,Mn III) 2 O 4 · 1.5 H 2 O; Buserite, MnO 2 ·nH 2 O; Hausmannite, Mn II Mn III 2 O 4; Manganite, Mn III O(OH)
The most stable are 53 Mn with a half-life of 3.7 million years, 54 Mn with a half-life of 312.2 days, and 52 Mn with a half-life of 5.591 days. All of the remaining radioactive isotopes have half-lives of less than three hours, and the majority of less than one minute.
Manganese(II,III) oxide is the chemical compound with formula Mn 3 O 4. Manganese is present in two oxidation states +2 and +3 and the formula is sometimes written as MnO·Mn 2 O 3. Mn 3 O 4 is found in nature as the mineral hausmannite.
Heating MnO 2 in air at below 800 °C produces α-Mn 2 O 3 (higher temperatures produce Mn 3 O 4). [5] γ-Mn 2 O 3 can be produced by oxidation followed by dehydration of manganese(II) hydroxide. [5] Many preparations of nano-crystalline Mn 2 O 3 have been reported, for example syntheses involving oxidation of Mn II salts or reduction of MnO 2 ...
Note that some words contain an ae which may not be written æ because the etymology is not from the Greek -αι-or Latin -ae-diphthongs. These include: In instances of aer (starting or within a word) when it makes the sound IPA [ɛə]/[eə] (air). Comes from the Latin āër, Greek ἀήρ. When ae makes the diphthong / eɪ / (lay) or / aɪ ...
[2] [3] Long thought to be antiferromagnetic , manganese telluride has been determined to be altermagnetic . [ 4 ] It has a Néel temperature of 307 K. [ 5 ]
MnCO 3 → MnO + CO 2. This calcining process is conducted anaerobically, lest Mn 2 O 3 form. An alternative route, most interest for demonstration purposes, is the "oxalate method". Also applicable to the synthesis of ferrous oxide and stannous oxide, it entails heating in an oxygen-free atmosphere (often CO 2), hydrated manganese(II) oxalate: [9]
MnCl 3 (OPPh 3) 2, a stable derivative form of MnCl 3. MnCl 3 can be stabilized by complexation to diverse Lewis bases, as has been established over the course of many years of study. [4] Meta stable acetonitrile-solvated Mn(III)Cl 3 can be prepared at room temperature by treating [Mn 12 O 12 (OAc) 16 (H 2 O) 4] with trimethylsilyl chloride. [5]