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In organic chemistry, peroxyacyl nitrates (also known as Acyl peroxy nitrates, APN or PANs) are powerful respiratory and eye irritants present in photochemical smog. They are nitrates produced in the thermal equilibrium between organic peroxy radicals by the gas -phase oxidation of a variety of volatile organic compounds (VOCs), or by aldehydes ...
Human health effects of eutrophication derive from two main issues excess nitrate in drinking water and exposure to toxic algae. [50] Nitrates in drinking water can cause blue baby syndrome in infants and can react with chemicals used to treat water to create disinfection by-products in drinking water. [ 51 ]
There is also evidence for shifts in the production of key intermediary volatile products, some of which have marked greenhouse effects (e.g., N 2 O and CH 4, reviewed by Breitburg in 2018, [15] due to the increase in global temperature, ocean stratification and deoxygenation, driving as much as 25 to 50% of nitrogen loss from the ocean to the ...
Peroxyacetyl nitrate is a peroxyacyl nitrate. It is a secondary pollutant present in photochemical smog. [1] It is thermally unstable and decomposes into peroxyethanoyl radicals and nitrogen dioxide gas. [2] It is a lachrymatory substance, meaning that it irritates the lungs and eyes. [3]
In the NO − 3 anion, the oxidation state of the central nitrogen atom is V (+5). This corresponds to the highest possible oxidation number of nitrogen. Nitrate is a potentially powerful oxidizer as evidenced by its explosive behaviour at high temperature when it is detonated in ammonium nitrate (NH 4 NO 3), or black powder, ignited by the shock wave of a primary explosive.
The WHO standard for drinking water is 50 mg NO − 3 L −1 for short-term exposure, and for 3 mg NO − 3 L −1 chronic effects. [64] Once it enters the human body, nitrate can react with organic compounds through nitrosation reactions in the stomach to form nitrosamines and nitrosamides , which are involved in some types of cancers (e.g ...
The effect of pesticides on soil microorganisms is impacted by the persistence, concentration, and toxicity of the applied pesticide, in addition to various environmental factors. [70] This complex interaction of factors makes it difficult to draw definitive conclusions about the interaction of pesticides with the soil ecosystem .
Nitrification inhibitors are also of interest from an environmental standpoint because of the production of nitrates and nitrous oxide from the nitrification process. Nitrous oxide (N 2 O), although its atmospheric concentration is much lower than that of CO 2, has a global warming potential of about 300 times greater than carbon dioxide and ...