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The main purpose of dimethyldichlorosilane is for use in the synthesis of silicones, an industry that was valued at more than $10 billion per year in 2005. It is also employed in the production of polysilanes, which in turn are precursors to silicon carbide . [ 3 ]
The dominant examples come from the Direct process, i.e., (CH 3) 4-x SiCl x. Another important member is trichlorosilane (SiHCl 3). Organosilanes are a class of charge-neutral organosilicon compounds. Example: tetramethylsilane (Si(CH 3) 4) By tradition, compounds with Si-O-Si bonds are usually not referred to as silanes. Instead, they are ...
The major product for the direct process should be dichlorodimethylsilane, Me 2 SiCl 2. However, many other products are formed. Unlike most reactions, this distribution is actually desirable because the product isolation is very efficient. [1] Each methylchlorosilane has specific and often substantial applications. Me 2 SiCl 2 is the most ...
Although proportionately a minor outlet, organosilicon compounds are widely used in organic synthesis. Notably trimethylsilyl chloride Me 3 SiCl is the main silylating agent. One classic method called the Flood reaction for the synthesis of this compound class is by heating hexaalkyldisiloxanes R 3 SiOSiR 3 with concentrated sulfuric acid and a ...
Dimethyldichlorosilane (Si(CH 3) 2 Cl 2) is a key precursor to cyclic (D 3, D 4, etc.) and linear siloxanes. [5]The main route to siloxane functional group is by hydrolysis of silicon chlorides:
One example is triethoxysilane: HSiCl 3 + 3 EtOH → HSi(OEt) 3 + 3 HCl. Organohydrosilanes can be prepared by partial hydrosilation of silane itself: SiH 4 + 3 C 2 H 4 → HSi(C 2 H 5) 3. In the laboratory, hydrosilanes classically are prepared by treating chlorosilanes with hydride reagents, such as lithium aluminium hydride:
Other acid-forming species, especially acetate, can replace chlorine in silicone synthesis with little difference in the chemistry of the finished polymer. These analogues of chlorosilanes are quite common in the sealants and adhesives marketed to consumers, and as precursors for medical-grade silicone, because of reduced toxicity.
In the cited example the Lewis acid TiCl 4 is used. First, the Lewis acid activates the aldehyde component followed by carbon-carbon bond formation between the enol silane and the activated aldehyde. With the loss of a chlorosilane the compound 1 is built. The desired product, a racemate of 2 and 3, is obtained by aqueous work-up. [3]