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Anisole undergoes electrophilic aromatic substitution reaction at a faster speed than benzene, which in turn reacts more quickly than nitrobenzene.The methoxy group is an ortho/para directing group, which means that electrophilic substitution preferentially occurs at these three sites.
In organic chemistry, a methoxy group is the functional group consisting of a methyl group bound to oxygen. This alkoxy group has the formula R−O−CH 3 . On a benzene ring , the Hammett equation classifies a methoxy substituent at the para position as an electron-donating group , but as an electron-withdrawing group if at the meta position.
The carbon on that is sp 3 hybridized and less electronegative than those that are sp 2 hybridized. They have overlap on the carbon–hydrogen bonds (or carbon–carbon bonds in compounds like tert-butylbenzene) with the ring p orbital. Hence they are more reactive than benzene and are ortho/para directors.
Ortho effect is an organic chemistry phenomenon where the presence of a chemical group at the at ortho position or the 1 and 2 position of a phenyl ring, relative to the carboxylic compound changes the chemical properties of the compound.
Formyl functional group is shown in blue. Formylation refers to any chemical processes in which a compound is functionalized with a formyl group (-CH=O). In organic chemistry, the term is most commonly used with regards to aromatic compounds (for example the conversion of benzene to benzaldehyde in the Gattermann–Koch reaction).
The methyl group can be rotated either at 5° or 13° out of the plane of the benzene ring. The ortho nitro group is rotated at 3° or 35°. The para nitro group is close to parallel with the ring plane. [2] The specific heat of solid 2,4-dinitroanisole is given by C p (Jmol −1 K −1) = 0.3153 + 0.00265T (T in K).
Nitrobenzene is an aromatic nitro compound and the simplest of the nitrobenzenes, with the chemical formula C 6 H 5 NO 2. It is a water-insoluble pale yellow oil with an almond-like odor. It freezes to give greenish-yellow crystals. It is produced on a large scale from benzene as a precursor to aniline.
4-Anisaldehyde, or p-Anisaldehyde, is an organic compound with the formula CH 3 OC 6 H 4 CHO. The molecule consists of a benzene ring with a formyl and a methoxy group. It is a colorless liquid with a strong aroma. It provides sweet, floral and strong aniseed odor. Two isomers of 4-anisaldehyde are known, ortho-anisaldehyde and meta ...