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tert-Butyl bromide (also referred to as 2-bromo-2-methylpropane) is an organic compound with the formula Me 3 CBr (Me = methyl). The molecule features a tert-butyl group attached to a bromide substituent. This organobromine compound is used as a standard reagent in synthetic organic chemistry. It is a colorless liquid.
The molecular formula C 4 H 9 Br, (molar mass: 137.02 g/mol, exact mass: 135.9888 u) may refer to: 1-Bromobutane; 2-Bromobutane; tert-Butyl bromide; 1-bromo-2 ...
Both compounds share the molecular formula C 4 H 9 Br. 2-Bromobutane is also known as sec-butyl bromide or methylethylbromomethane. Because it contains bromine, a halogen, it is part of a larger class of compounds known as alkyl halides. It is a colorless liquid with a pleasant odor.
2-Bromo-2-methylpropane (tert-butyl bromide) Index of chemical compounds with the same name This set index article lists chemical compounds articles associated with the same name.
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
The intermediate in this synthesis is di-tert-butylcyclopentadiene. This compound is conveniently prepared by alkylation of cyclobutadiene with tert-butyl bromide under phase-transfer conditions. [2] [1] Illustrative of the unusual complexes made possible with these bulky ligands is molecular iron nitrido complex (t Bu 3 C 5 H 2) 2 Fe 2 N 2. [3]
Bromobutane (molecular formula: C 4 H 9 Br, molar mass: 137.02 g/mol) may refer to either of two chemical compounds: 1-Bromobutane (n-butyl bromide) 2-Bromobutane (sec-butyl bromide or methylethylbromomethane)
1-Bromobutane is the organobromine compound with the formula CH 3 (CH 2) 3 Br. It is a colorless liquid, although impure samples appear yellowish. It is insoluble in water, but soluble in organic solvents. It is primarily used as a source of the butyl group in organic synthesis. It is one of several isomers of butyl bromide.