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The equation was postulated by Schrödinger based on a postulate of Louis de Broglie that all matter has an associated matter wave. The equation predicted bound states of the atom in agreement with experimental observations. [4]: II:268 The Schrödinger equation is not the only way to study quantum mechanical systems and make predictions.
The Schrödinger equation determines how wave functions evolve over time, and a wave function behaves qualitatively like other waves, such as water waves or waves on a string, because the Schrödinger equation is mathematically a type of wave equation. This explains the name "wave function", and gives rise to wave–particle duality.
The significance ascribed to the wave function varies from interpretation to interpretation and even within an interpretation (such as the Copenhagen interpretation). If the wave function merely encodes an observer's knowledge of the universe, then the wave function collapse corresponds to the receipt of new information.
In the Schrödinger picture, the wave function or field is the solution to the Schrödinger equation; = ^ one of the postulates of quantum mechanics. All relativistic wave equations can be constructed by specifying various forms of the Hamiltonian operator Ĥ describing the quantum system .
In quantum mechanics, the Schrödinger equation describes how a system changes with time. It does this by relating changes in the state of the system to the energy in the system (given by an operator called the Hamiltonian). Therefore, once the Hamiltonian is known, the time dynamics are in principle known.
The quantum wave equation can be solved using functions of position, (), or using functions of momentum, () and consequently the superposition of momentum functions are also solutions: = + The position and momentum solutions are related by a linear transformation, a Fourier transformation. This transformation is itself a quantum superposition ...
The wave packet becomes more de-localized: it is now on both sides of the barrier and lower in maximum amplitude, but equal in integrated square-magnitude, meaning that the probability the particle is somewhere remains unity. The wider the barrier and the higher the barrier energy, the lower the probability of tunneling.
In the framework of the de Broglie–Bohm theory, the quantum potential is a term within the Schrödinger equation which acts to guide the movement of quantum particles. . The quantum potential approach introduced by Bohm [1] [2] provides a physically less fundamental exposition of the idea presented by Louis de Broglie: de Broglie had postulated in 1925 that the relativistic wave function ...