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3 Ag + 4 HNO 3 (cold and diluted) → 3 AgNO 3 + 2 H 2 O + NO Ag + 2 HNO 3 (hot and concentrated) → AgNO 3 + H 2 O + NO 2. The structure of silver nitrate has been examined by X-ray crystallography several times. In the common orthorhombic form stable at ordinary temperature and pressure, the silver atoms form pairs with Ag---Ag contacts of 3 ...
Sodium thiocyanate (sometimes called sodium sulphocyanide) is the chemical compound with the formula NaSCN. This colorless deliquescent salt is one of the main sources of the thiocyanate anion.
Sodium iodide (chemical formula NaI) is an ionic compound formed from the chemical reaction of sodium metal and iodine.Under standard conditions, it is a white, water-soluble solid comprising a 1:1 mix of sodium cations (Na +) and iodide anions (I −) in a crystal lattice.
Silver nitrite is produced from the reaction between silver nitrate and an alkali nitrite, such as sodium nitrite. [3] Silver nitrite is much less soluble in water than silver nitrate, and a solution of silver nitrate will readily precipitate silver nitrite upon addition of sodium nitrite:
Sodium and potassium form KNa 2 and NaK. NaK is 40–90% potassium and it is liquid at ambient temperature. It is an excellent thermal and electrical conductor. Sodium-calcium alloys are by-products of the electrolytic production of sodium from a binary salt mixture of NaCl-CaCl 2 and ternary mixture NaCl-CaCl 2-BaCl 2.
2 HNO 3 + Na 2 CO 3 → 2 NaNO 3 + H 2 O + CO 2 HNO 3 + NaHCO 3 → NaNO 3 + H 2 O + CO 2. or also by neutralizing it with sodium hydroxide (however, this reaction is very exothermic): HNO 3 + NaOH → NaNO 3 + H 2 O. or by mixing stoichiometric amounts of ammonium nitrate and sodium hydroxide, sodium bicarbonate or sodium carbonate: NH 4 NO 3 ...
For AgBr and AgI, the K sp values are 5.2 x 10 −13 and 8.3 x 10 −17, respectively. Silver bromide (slightly yellowish white) and silver iodide (bright yellow) are also significantly more photosensitive than is AgCl. [1] [4]: 46 AgCl quickly darkens on exposure to light by disintegrating into elemental chlorine and metallic silver.
AgF 3 can be prepared by treating a solution containing tetrafluoroargentate(III) ions in anhydrous hydrogen fluoride with boron trifluoride; [2] the potassium tetrafluoroargentate(III) was prepared by heating a stoichiometric mix of potassium and silver nitrate in a sealed container filled with pressurised fluorine gas at 400C for 24 hours, twice.