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Triethylamine is prepared by the alkylation of ammonia with ethanol: [10]. NH 3 + 3 C 2 H 5 OH → N(C 2 H 5) 3 + 3 H 2 O. The pK a of protonated triethylamine is 10.75, [4] and it can be used to prepare buffer solutions at that pH.
A variety of amines and nitrogen heterocycles are useful bases of moderate strength (pK a of conjugate acid around 10-13) . N,N-Diisopropylethylamine (DIPEA, also called Hünig's Base [1]), pK a = 10.75
DIPEA is a sterically hindered organic base that is commonly employed as a proton scavenger. Thus, like 2,2,6,6-tetramethylpiperidine and triethylamine, DIPEA is a good base but a poor nucleophile, DIPEA has low solubility in water, which makes it very easily recovered in commercial processes, a combination of properties that makes it a useful organic reagent.
Triethanolamine, or TEOA, is an organic compound with the chemical formula N(CH 2 CH 2 OH) 3.It is a colourless, viscous liquid. It is both a tertiary amine and a triol.A triol is a molecule with three alcohol groups.
4-Dimethylaminopyridine (DMAP) is a derivative of pyridine with the chemical formula (CH 3) 2 NC 5 H 4 N. This white solid is of interest because it is more basic than pyridine, owing to the resonance stabilisation from the NMe 2 substituent.
Tetraethylammonium (TEA) is a quaternary ammonium cation with the chemical formula [Et 4 N] +, consisting of four ethyl groups (−C 2 H 5, denoted Et) attached to a central nitrogen atom.
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As a reagent in organic chemistry, DBU is used as a ligand and base. As a base, protonation occurs at the imine nitrogen. [5] Lewis acids also attach to the same nitrogen. [6]