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Thus, the fluorescence quantum yield is affected if the rate of any non-radiative pathway changes. The quantum yield can be close to unity if the non-radiative decay rate is much smaller than the rate of radiative decay, that is k f > k nr. [2] Fluorescence quantum yields are measured by comparison to a standard of known quantum yield. [2]
The Born rule is a postulate of quantum mechanics that gives the probability that a measurement of a quantum system will yield a given result. In one commonly used application, it states that the probability density for finding a particle at a given position is proportional to the square of the amplitude of the system's wavefunction at that position.
Quantum state tomography is a process by which, given a set of data representing the results of quantum measurements, a quantum state consistent with those measurement results is computed. [50] It is named by analogy with tomography , the reconstruction of three-dimensional images from slices taken through them, as in a CT scan .
A graph showing variation of quantum efficiency with wavelength of a CCD chip from Wide Field and Planetary Camera 2, formerly installed on the Hubble Space Telescope.. The term quantum efficiency (QE) may apply to incident photon to converted electron (IPCE) ratio [1] of a photosensitive device, or it may refer to the TMR effect of a magnetic tunnel junction.
A corollary of Kasha's rule is the Vavilov rule, which states that the quantum yield of luminescence is generally independent of the excitation wavelength. [4] [7] This can be understood as a consequence of the tendency – implied by Kasha's rule – for molecules in upper states to relax to the lowest excited state non-radiatively.
Bohmian mechanics reformulates quantum mechanics to make it deterministic, at the price of adding a force due to a "quantum potential". It attributes to each physical system not only a wave function but in addition a real position that evolves deterministically under a nonlocal guiding equation.
Bonds can provide passive income, some of which may be tax-free if you're investing in municipal bonds. The tax-equivalent yield formula can be a useful tool for comparing taxable and tax-free ...
In quantum mechanics, the expectation value is the probabilistic expected value of the result (measurement) of an experiment. It can be thought of as an average of all the possible outcomes of a measurement as weighted by their likelihood, and as such it is not the most probable value of a measurement; indeed the expectation value may have zero probability of occurring (e.g. measurements which ...