Search results
Results from the WOW.Com Content Network
The generation of heat in large quantities accompanies most explosive chemical reactions. The exceptions are called entropic explosives and include organic peroxides such as acetone peroxide. [6] It is the rapid liberation of heat that causes the gaseous products of most explosive reactions to expand and generate high pressures. This rapid ...
According to the IUPAC, an exothermic reaction is "a reaction for which the overall standard enthalpy change ΔH⚬ is negative". [4] Some examples of exothermic process are fuel combustion, condensation and nuclear fission, [5] which is used in nuclear power plants to release large amounts of energy. [6]
The most widely used explosives are condensed liquids or solids converted to gaseous products by explosive chemical reactions and the energy released by those reactions. The gaseous products of complete reaction are typically carbon dioxide , steam , and nitrogen . [ 17 ]
Sensitivity, stability and brisance are three of the most significant properties of explosives that affect their use and application. All explosive compounds have a certain amount of energy required to initiate, analogous to the minimum ignition energy of fuel-air mixtures. If an explosive is too sensitive, it may go off accidentally.
A contact explosive is a chemical substance that explodes violently when it is exposed to a relatively small amount of energy (e.g. friction, pressure, sound, light). Though different contact explosives have varying amounts of energy sensitivity , they are all much more sensitive relative to other kinds of explosives.
The most common use of PETN is as an explosive with high brisance. It is a secondary explosive , meaning it is more difficult to detonate than primary explosives , so dropping or igniting it will typically not cause an explosion (at standard atmospheric pressure it is difficult to ignite and burns vigorously), but is more sensitive to shock and ...
The enthalpy of a chemical system is essentially its energy. The enthalpy change ΔH for a reaction is equal to the heat q transferred out of (or into) a closed system at constant pressure without in- or output of electrical energy. Heat production or absorption in a chemical reaction is measured using calorimetry, e.g. with a bomb calorimeter.
The reaction is usually endothermic as heat is required to break chemical bonds in the compound undergoing decomposition. If decomposition is sufficiently exothermic, a positive feedback loop is created producing thermal runaway and possibly an explosion or other chemical reaction. Thermal decomposition is a chemical reaction where heat is a ...