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Since hydrochloric acid was already fully settled as an important chemical in numerous applications, the commercial interest initiated other production methods, some of which are still used today. After 2000, hydrochloric acid is mostly made by absorbing by-product hydrogen chloride from industrial organic compounds production. [25] [26] [7]
The hydrochloric acid provides a ready supply of chloride ions (Cl −), which react with the gold ions to produce tetrachloroaurate(III) anions ([AuCl 4] −), also in solution. The reaction with hydrochloric acid is an equilibrium reaction that favors formation of tetrachloroaurate(III) anions.
Most hydrogen chloride is consumed in the production of hydrochloric acid. It is also used in the production of vinyl chloride and many alkyl chlorides. [13] Trichlorosilane, a precursor to ultrapure silicon, is produced by the reaction of hydrogen chloride and silicon at around 300 °C. [18] Si + 3 HCl → HSiCl 3 + H 2
For every mole of chlorine produced, one mole of hydrogen is produced. Much of this hydrogen is used to produce hydrochloric acid, ammonia, hydrogen peroxide, or is burned for power and/or steam production. [3]
The Leblanc process, which was invented by Nicolas Leblanc around 1790, begins with the decomposition of sodium chloride by sulfuric acid, by which sodium sulfate and hydrochloric acid are produced. The sodium sulfate is afterwards fired with calcium carbonate and coal. Sodium carbonate can be extracted from this mixture by washing the mixture ...
Potassium permanganate can be used to generate chlorine gas when concentrated hydrochloric acid is added to it: 2KMn04 + 16HCl —> 2KCl + 2MnCl2 + 8H2O + 5Cl2 This process has been investigated by Venable & Jackson and fails if the concentation of the hydrochloric acid solution drops below 2mM Venable, F. P.; Jackson, D.H. (1920). "The ...
The commercially most relevant field of application for HCl regeneration processes is the recovery of HCl from waste pickle liquors from carbon-steel pickling lines. Other applications include the production of metal oxides such as, but not limited, to Al 2 O 3 and MgO, as well as rare-earth oxides, by pyrohydrolysis of aqueous metal chloride or rare-earth chloride solutions.
The main steps in this process are the production of chlorobenzene from benzene, hydrochloric acid and oxygen, and the subsequent hydrolysis of chlorobenzene to phenol. [4] The first step uses either a copper or iron chloride catalyst and exposes the materials to air at 200–250 °C.