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A demonstration of slaking of quicklime as a strongly exothermic reaction. Drops of water are added to pieces of quicklime. After a while, a pronounced exothermic reaction occurs ("slaking of lime"). The temperature can reach up to some 300 °C (572 °F). The major use of quicklime is in the basic oxygen steelmaking (BOS) process. Its usage ...
The integral heat of dissolution is defined as a process of obtaining a certain amount of solution with a final concentration. The enthalpy change in this process, normalized by the mole number of solute, is evaluated as the molar integral heat of dissolution. Mathematically, the molar integral heat of dissolution is denoted as:
When water is heated to well over 2,000 °C (2,270 K; 3,630 °F), a small percentage of it will decompose into OH, monatomic oxygen, monatomic hydrogen, O 2, and H 2. [ 3 ] The compound with the highest known decomposition temperature is carbon monoxide at ≈3870 °C (≈7000 °F).
Calcium hydroxide is modestly soluble in water, as seen for many dihydroxides. Its solubility increases from 0.66 g/L at 100 °C to 1.89 g/L at 0 °C. [8] Its solubility product K sp of 5.02 × 10 −6 at 25 °C, [1] its dissociation in water is large enough that its solutions are basic according to the following dissolution reaction:
The theoretical heat (the standard enthalpy) of reaction required to make high-calcium lime is around 3.15 MJ per kg of lime, so the batch kilns were only around 20% efficient. The key to development in efficiency was the invention of continuous kilns, avoiding the wasteful heat-up and cool-down cycles of the batch kilns.
A typical phase diagram.The solid green line applies to most substances; the dashed green line gives the anomalous behavior of water. In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium. [1]
In thermodynamics, the enthalpy of mixing (also heat of mixing and excess enthalpy) is the enthalpy liberated or absorbed from a substance upon mixing. [1] When a substance or compound is combined with any other substance or compound, the enthalpy of mixing is the consequence of the new interactions between the two substances or compounds. [ 1 ]
Pure lime is soluble in water containing carbonic acid, a natural, weak acid which is a solution of carbon dioxide in water and acid rain so it will slowly wash away, but this characteristic also produces autogenous or self-healing process where the dissolved lime can flow into cracks in the material and be redeposited, automatically repairing ...