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HDPE is known for its high strength-to-density ratio. [4] The density of HDPE ranges from 930 to 970 kg/m 3. [5] Although the density of HDPE is only marginally higher than that of low-density polyethylene, HDPE has little branching, giving it stronger intermolecular forces and tensile strength (38 MPa versus 21 MPa) than LDPE. [6]
The onset of thermal degradation dictates the maximum temperature at which a polymer can be used. It is an important limitation in how the polymer is manufactured and processed. For instance, polymers become less viscous at higher temperatures which makes injection moulding easier and faster, but thermal degradation places a ceiling temperature ...
In the so-called Engel process, a mixture of HDPE and 2% [42] peroxide is at first mixed at low temperatures in an extruder and then crosslinked at high temperatures (between 200 and 250 °C). [41] The peroxide decomposes to peroxide radicals (RO•), which abstract (remove) hydrogen atoms from the polymer chain, leading to radicals .
Ultra-high-molecular-weight polyethylene (UHMWPE, UHMW) is a subset of the thermoplastic polyethylene.Also known as high-modulus polyethylene (HMPE), it has extremely long chains, with a molecular mass usually between 3.5 and 7.5 million amu. [1]
A Assuming an altitude of 194 metres above mean sea level (the worldwide median altitude of human habitation), an indoor temperature of 23 °C, a dewpoint of 9 °C (40.85% relative humidity), and 760 mmHg sea level–corrected barometric pressure (molar water vapor content = 1.16%). B Calculated values *Derived data by calculation.
Ordinary ice shows NTE in its hexagonal and cubic phases at very low temperatures (below –200 °C). [9] In its liquid form, pure water also displays negative thermal expansivity below 3.984 °C. ALLVAR Alloy 30, a titanium-based alloy, shows NTE over a wide temperature range, with a -30 ppm/°C instantaneous coefficient of thermal expansion ...
Polymer degradation is the reduction in the physical properties of a polymer, such as strength, caused by changes in its chemical composition.Polymers and particularly plastics are subject to degradation at all stages of their product life cycle, including during their initial processing, use, disposal into the environment and recycling. [1]
The name high temperature plastics is in use due to their continuous service temperature (CST), which is always higher than 150 °C by definition (although this is not their only feature, as it can be seen above). The term "polymers" is often used instead of "plastics" because both terms are used as synonyms in the field of engineering.
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