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Raoult's law (/ ˈ r ɑː uː l z / law) is a relation of physical chemistry, with implications in thermodynamics.Proposed by French chemist François-Marie Raoult in 1887, [1] [2] it states that the partial pressure of each component of an ideal mixture of liquids is equal to the vapor pressure of the pure component (liquid or solid) multiplied by its mole fraction in the mixture.
The vapor pressure affects the solute shown by Raoult's Law while the free energy change and chemical potential are shown by Gibbs free energy. Most solutes remain in the liquid phase and do not enter the gas phase, except at very high temperatures. In terms of vapor pressure, a liquid boils when its vapor pressure equals the surrounding pressure.
This indicates that all colligative properties have a common feature, namely that they are related only to the number of solute molecules relative to the number of solvent molecules and not to the nature of the solute. [4] Colligative properties include: Relative lowering of vapor pressure (Raoult's law) Elevation of boiling point
The simplest definition is that an ideal solution is a solution for which each component obeys Raoult's law = for all compositions. Here p i {\displaystyle p_{i}} is the vapor pressure of component i {\displaystyle i} above the solution, x i {\displaystyle x_{i}} is its mole fraction and p i ∗ {\displaystyle p_{i}^{*}} is the vapor pressure ...
Köhler theory combines the Kelvin effect, which describes the change in vapor pressure due to a curved surface, with Raoult's Law, which relates the vapor pressure to the solute concentration. [1] [2] [3] It was initially published in 1936 by Hilding Köhler, Professor of Meteorology in the Uppsala University.
An osmotic coefficient is a quantity which characterises the deviation of a solvent from ideal behaviour, referenced to Raoult's law.It can be also applied to solutes. Its definition depends on the ways of expressing chemical composition of mixtures.
In thermodynamics, an activity coefficient is a factor used to account for deviation of a mixture of chemical substances from ideal behaviour. [1] In an ideal mixture, the microscopic interactions between each pair of chemical species are the same (or macroscopically equivalent, the enthalpy change of solution and volume variation in mixing is zero) and, as a result, properties of the mixtures ...
Raoult's law – Law of thermodynamics for vapour pressure of a mixture; Relative volatility – Comparative volatility of components in a solution; Vapor–liquid equilibrium – Concentration of a vapor in contact with its liquid; Volatile organic compound – Organic chemicals having a high vapor pressure at room temperature