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The low solubility of silver iodide and lead iodide reflects the covalent character of these metal iodides. A test for the presence of iodide ions is the formation of yellow precipitates of these compounds upon treatment of a solution of silver nitrate or lead(II) nitrate. [2] Aqueous solutions of iodide salts dissolve iodine better than pure ...
This is an accepted version of this page This is the latest accepted revision, reviewed on 9 January 2025. This article is about the chemical element. For other uses, see Iodine (disambiguation). Chemical element with atomic number 53 (I) Iodine, 53 I Iodine Pronunciation / ˈ aɪ ə d aɪ n, - d ɪ n, - d iː n / (EYE -ə-dyne, -din, -deen) Appearance lustrous metallic gray solid, black ...
(Nonetheless, nitrogen triiodide is named as an iodide as it is analogous to the other nitrogen trihalides.) [7] Given the large size of the iodide anion and iodine's weak oxidising power, high oxidation states are difficult to achieve in binary iodides, the maximum known being in the pentaiodides of niobium, tantalum, and protactinium. Iodides ...
These iodine compounds are hypervalent because the iodine atom formally contains in its valence shell more than the 8 electrons required for the octet rule. Hypervalent iodine oxyanions are known for oxidation states +1, +3, +5, and +7; organic analogues of these moieties are known for each oxidation state except +7.
For example, in the molecules represented by CH 3 X, where X is a halide, the carbon-X bonds have strengths, or bond dissociation energies, of 115, 83.7, 72.1, and 57.6 kcal/mol for X = fluoride, chloride, bromide, and iodide, respectively. [2] Of the halides, iodide usually is the best leaving group.
These may be metal salts containing iodide ion such as potassium iodide, or more covalent iodides such as phosphorus triiodide. See also. Category:Metal halides;
There are 40 known isotopes of iodine (53 I) from 108 I to 147 I; all undergo radioactive decay except 127 I, which is stable. Iodine is thus a monoisotopic element.. Its longest-lived radioactive isotope, 129 I, has a half-life of 16.14 million years, which is far too short for it to exist as a primordial nuclide.
The following exergonic equilibrium gives rise to the triiodide ion: . I 2 + I − ⇌ I − 3. In this reaction, iodide is viewed as a Lewis base, and the iodine is a Lewis acid.The process is analogous to the reaction of S 8 with sodium sulfide (which forms polysulfides) except that the higher polyiodides have branched structures.