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The Bohr model of the hydrogen atom (Z = 1) or a hydrogen-like ion (Z > 1), where the negatively charged electron confined to an atomic shell encircles a small, positively charged atomic nucleus and where an electron jumps between orbits, is accompanied by an emitted or absorbed amount of electromagnetic energy (hν). [1]
The initial idea of the BKS theory originated with Slater, [13] who proposed to Bohr and Kramers the following elements of a theory of emission and absorption of radiation by atoms, to be developed during his stay in Copenhagen: Emission and absorption of electromagnetic radiation by matter is realized in agreement with Einstein's photon concept;
The Bohr model was later replaced by quantum mechanics in which the electron occupies an atomic orbital rather than an orbit, but the allowed energy levels of the hydrogen atom remained the same as in the earlier theory. Spectral emission occurs when an electron transitions, or jumps, from a higher energy state to a lower energy state.
In physics and chemistry, the Lyman series is a hydrogen spectral series of transitions and resulting ultraviolet emission lines of the hydrogen atom as an electron goes from n ≥ 2 to n = 1 (where n is the principal quantum number), the lowest energy level of the electron (groundstate).
Bohr was also a philosopher and a promoter of scientific research. Bohr developed the Bohr model of the atom, in which he proposed that energy levels of electrons are discrete and that the electrons revolve in stable orbits around the atomic nucleus but can jump from one energy level (or orbit) to another. Although the Bohr model has been ...
Einstein developed the statistical mechanics for Bohr-model atoms interacting with electromagnetic radiation, leading to absorption and two kinds of emission, spontaneous and stimulated emission. But for Bohr the important result was the use of classical analogies and the Bohr atomic model to fix inconsistencies in Planck's derivation of the ...
A quantum jump is the abrupt transition of a quantum system (atom, molecule, atomic nucleus) from one quantum state to another, from one energy level to another. When the system absorbs energy, there is a transition to a higher energy level (); when the system loses energy, there is a transition to a lower energy level.
In the simplified Rutherford Bohr model of the hydrogen atom, the Balmer lines result from an electron jump between the second energy level closest to the nucleus, and those levels more distant. Shown here is a photon emission. The 3→2 transition depicted here produces H-alpha, the first line of the Balmer series.