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  2. Molar concentration - Wikipedia

    en.wikipedia.org/wiki/Molar_concentration

    Molar concentration (also called molarity, amount concentration or substance concentration) is a measure of the concentration of a chemical species, in particular, of a solute in a solution, in terms of amount of substance per unit volume of solution. In chemistry, the most commonly used unit for molarity is the number of moles per liter ...

  3. Defining equation (physical chemistry) - Wikipedia

    en.wikipedia.org/wiki/Defining_equation...

    the number of moles of the substance n, partial pressure of a gas in a gaseous mixture p (or P), some form of energy of a substance (for chemistry enthalpy H is common), entropy of a substance S. the electronegativity of an atom or chemical bond χ.

  4. Molality - Wikipedia

    en.wikipedia.org/wiki/Molality

    The term molality is formed in analogy to molarity which is the molar concentration of a solution. The earliest known use of the intensive property molality and of its adjectival unit, the now-deprecated molal, appears to have been published by G. N. Lewis and M. Randall in the 1923 publication of Thermodynamics and the Free Energies of Chemical Substances. [3]

  5. Sigma bond - Wikipedia

    en.wikipedia.org/wiki/Sigma_bond

    In chemistry, sigma bondsbonds) or sigma overlap are the strongest type of covalent chemical bond. [1] They are formed by head-on overlapping between atomic orbitals along the internuclear axis. Sigma bonding is most simply defined for diatomic molecules using the language and tools of symmetry groups. In this formal approach, a σ-bond is ...

  6. Molecular orbital diagram - Wikipedia

    en.wikipedia.org/wiki/Molecular_orbital_diagram

    This MO is called the bonding orbital and its energy is lower than that of the original atomic orbitals. A bond involving molecular orbitals which are symmetric with respect to any rotation around the bond axis is called a sigma bond (σ-bond). If the phase cycles once while rotating round the axis, the bond is a pi bond (π-bond).

  7. Collision theory - Wikipedia

    en.wikipedia.org/wiki/Collision_theory

    Collision theory. Reaction rate tends to increase with concentration phenomenon explained by collision theory. Collision theory is a principle of chemistry used to predict the rates of chemical reactions. It states that when suitable particles of the reactant hit each other with the correct orientation, only a certain amount of collisions ...

  8. Conductivity (electrolytic) - Wikipedia

    en.wikipedia.org/wiki/Conductivity_(electrolytic)

    As the concentration is increased however, the conductivity no longer rises in proportion. Moreover, Kohlrausch also found that the limiting conductivity of an electrolyte; λ 0 + and λ 0 − are the limiting molar conductivities of the individual ions. The following table gives values for the limiting molar conductivities for some selected ...

  9. Molar conductivity - Wikipedia

    en.wikipedia.org/wiki/Molar_conductivity

    The molar conductivity of an electrolyte solution is defined as its conductivity divided by its molar concentration. [1][2] where: c is the molar concentration of the electrolyte. The SI unit of molar conductivity is siemens metres squared per mole (S m 2 mol −1). [2]