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A polycarbonate is an oxocarbon dianion consisting of a chain of carbonate units, where successive carbonyl groups are directly linked to each other by shared additional oxygen atoms. That is, they are the conjugate bases of polycarbonic acids , the conceptual anhydrides of carbonic acid , or polymers of carbon dioxide .
Example Bjerrum plot: Change in carbonate system of seawater from ocean acidification.. A Bjerrum plot (named after Niels Bjerrum), sometimes also known as a Sillén diagram (after Lars Gunnar Sillén), or a Hägg diagram (after Gunnar Hägg) [1] is a graph of the concentrations of the different species of a polyprotic acid in a solution, as a function of pH, [2] when the solution is at ...
Polycarbonate is commonly used in eye protection, as well as in other projectile-resistant viewing and lighting applications that would normally indicate the use of glass, but require much higher impact-resistance. Polycarbonate lenses also protect the eye from UV light.
In this equation, k is the number of monomers in the chain, [1] and 0<a<1 is an empirically determined constant related to the fraction of unreacted monomer remaining. [ 2 ] The form of this distribution implies is that shorter polymers are favored over longer ones — the chain length is geometrically distributed .
For example, if narrow molar mass distribution standards are available for polystyrene, these can be used to construct a calibration curve (typically vs. retention volume ) in eg. toluene at 40 °C. This calibration can then be used to determine the "polystyrene equivalent" molecular weight of a polyethylene sample if the Mark-Houwink ...
The simplest case refers to the formation of a strictly linear polymer by the reaction (usually by condensation) of two monomers in equimolar quantities. An example is the synthesis of nylon-6,6 whose formula is [−NH−(CH 2) 6 −NH−CO−(CH 2) 4 −CO−] n from one mole of hexamethylenediamine, H 2 N(CH 2) 6 NH 2, and one mole of adipic acid, HOOC−(CH 2) 4 −COOH.
Such losses become particularly significant, for example, in metals at short (e.g. visible) wavelengths, and must be included in any description of the refractive index. Refraction, critical angle and total internal reflection of light at the interface between two media.
They can be used in machinery, auto-industry, and medical applications. For example, the cockpit canopy of F-22 Raptor is made of high optical quality polycarbonate. Polysulfides have outstanding oil and solvent resistance, good gas impermeability, good resistance to aging and ozone. However, it smells bad, and it shows low tensile strength as ...