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Although tabulated values are usually corrected to 298 K, that correction is often smaller than the uncertainty in the measured value. The heat of vaporization is temperature-dependent, though a constant heat of vaporization can be assumed for small temperature ranges and for reduced temperature T r ≪ 1.
J.A. Dean (ed.), Lange's Handbook of Chemistry (15th Edition), McGraw-Hill, 1999; Section 6, Thermodynamic Properties; Table 6.4, Heats of Fusion, Vaporization, and Sublimation and Specific Heat at Various Temperatures of the Elements and Inorganic Compounds
L is the latent heat of vaporization at the temperature T, T C is the critical temperature, L 0 is the parameter that is equal to the heat of vaporization at zero temperature (T → 0), tanh is the hyperbolic tangent function. This equation was obtained in 1955 by Yu. I. Shimansky, at first empirically, and later derived theoretically.
The higher heating value takes into account the latent heat of vaporization of water in the combustion products, and is useful in calculating heating values for fuels where condensation of the reaction products is practical (e.g., in a gas-fired boiler used for space heat). In other words, HHV assumes all the water component is in liquid state ...
Finally, Black increased the temperature of a mass of water, then vaporized an equal mass of water by even heating. He showed that 830 “degrees of heat” was needed for the vaporization; again based on the time required. The modern value for the heat of vaporization of water would be 967 “degrees of heat” on the same scale. [19]
of vaporization, Δ vap H o: 47.5 kJ/mol Std entropy change of vaporization, Δ vap S o: 126.6 J/(mol·K) Solid properties Std enthalpy change of formation, Δ f H o solid-763 kJ/mol Standard molar entropy, S o solid: 112.7 J/(mol K) Heat capacity, c p: 106.3 J/(mol K) at –124 °C Liquid properties Std enthalpy change of formation, Δ f H o ...
Heat capacity, c p? J/(mol K) Liquid properties Standard enthalpy change of formation, Δ f H o liquid: −460 kJ/mol Standard molar entropy, S o liquid: 166.9 J/(mol·K) Heat capacity, c p: 149.5 J/(mol·K) Gas properties Standard enthalpy change of formation, Δ f H o gas: −3955.4 kJ/mol Standard molar entropy, S o gas: 311.8 J/(mol·K ...
Heat content data, heat of vaporization, and entropy values are relative to the liquid state at 0 °C temperature and 3483 kPa pressure. To convert heat values to joules per mole values, multiply by 44.095 g/mol. To convert densities to moles per liter, multiply by 22.678 cm 3 mol/(L·g).