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The salt is obtained by partial neutralization of phosphoric acid. The pK a of monosodium phosphate is 6.8-7.2 (depending on the physicochemical characteristics during pK a determination). [2] Heating this salt above 169 °C gives disodium pyrophosphate: 2 NaH 2 PO 4 → Na 2 H 2 P 2 O 7 + H 2 O. When heated at 550 °C, anhydrous trisodium ...
An amphiprotic molecule (or ion) can either donate or accept a proton, thus acting either as an acid or a base. Water, amino acids, hydrogencarbonate ion (or bicarbonate ion) HCO − 3, dihydrogen phosphate ion H 2 PO − 4, and hydrogensulfate ion (or bisulfate ion) HSO − 4 are common examples of amphiprotic species. Since they can donate a ...
A typical derivative is the salt [NH 4][HP(O) 2 OH]. [7] [6] Many related salts are known, e.g., RbHPHO 3, CsHPHO 3, TlHPHO 3. These salts are prepared by treating phosphorous acid with the metal carbonate. These compounds contain a layer polymeric anion consisting of HPO 3 tetrahedra linked by hydrogen bonds. These layers are interleaved by ...
The single-bonded oxygen atoms that are not shared are completed with acidic hydrogen atoms. The general formula of a phosphoric acid is H n+2−2x P n O 3n+1−x, where n is the number of phosphorus atoms and x is the number of fundamental cycles in the molecule's structure, between 0 and n + 2 / 2 . Pyrophosphate anion. Trimethyl ...
Phosphate binds to metals through one, two, three, or all four oxygen atoms. The bidentate coordination mode is common. The second and third pK a 's of phosphoric acid, pK a2 and pK a3, are 7.2 and 12.37, respectively. It follows that HPO 2− 4 and PO 3− 4 are sufficiently basic to serve as ligands. The examples below confirm this expectation.
Some compounds, such as salts of the chain-polymeric ion, Mo 2 O 2− 7 even contain both tetrahedral and octahedral units. [ 5 ] [ 6 ] Edge-sharing is common in ions containing octahedral building blocks and the octahedra are usually distorted to reduce the strain at the bridging oxygen atoms.
The commonly encountered salt is the pentahydrate. [1] A derivative of phosphorous acid (HP(O)(OH) 2), it contains the anion HPO 3 2−. Its common name suggests that it contains an acidic hydrogen atom, as in sodium hydrogen carbonate. However, this name is misleading as the hydrogen atom is not acidic, being bonded to phosphorus rather than ...
Heteropolymetalates: K 5 [IMo 6 O 24]·nH 2 O Ag 7 [PV 12 O 36]·nH 2 O (NH 4) 4 [NiMo 6 O 24 H 6]·5H 2 O K 3 [CrMo 6 O 24 H 6]·nH 2 O (NH 4) 8 [CeMo 12 O 42]·8H 2 O. In chemistry, the heteropolymetalates are a subset of the polyoxometalates, which consist of three or more transition metal oxyanions linked together by shared oxygen atoms to form a closed 3-dimensional molecular framework.