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A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atoms, when they share electrons, is known as covalent bonding. [1] For many molecules, the sharing of ...
The electron cloud in a σ-bond between two unlike atoms is not uniform and is slightly displaced towards the more electronegative of the two atoms. This causes a permanent state of bond polarization, where the more electronegative atoms has a fractional negative charge (δ –) and the less electronegative atom has a fractional positive charge ...
The exchange or sharing of the electrons between two or more atoms is the main cause of chemical bonding. [17] In 1838, British natural philosopher Richard Laming first hypothesized the concept of an indivisible quantity of electric charge to explain the chemical properties of atoms. [3]
A single bond between two atoms corresponds to the sharing of one pair of electrons. The Hydrogen (H) atom has one valence electron. Two Hydrogen atoms can then form a molecule, held together by the shared pair of electrons. Each H atom now has the noble gas electron configuration of helium (He).
Electronegativity. Electrostatic potential map of a water molecule, where the oxygen atom has a more negative charge (red) than the positive (blue) hydrogen atoms. Electronegativity, symbolized as χ, is the tendency for an atom of a given chemical element to attract shared electrons (or electron density) when forming a chemical bond. [1]
Partial charges are created due to the asymmetric distribution of electrons in chemical bonds. For example, in a polar covalent bond like HCl, the shared electron oscillates between the bonded atoms. The resulting partial charges are a property only of zones within the distribution, and not the assemblage as a whole.
Coordinate covalent bond. In coordination chemistry, a coordinate covalent bond, [1] also known as a dative bond, [2] dipolar bond, [1] or coordinate bond[3] is a kind of two-center, two-electron covalent bond in which the two electrons derive from the same atom. The bonding of metal ions to ligands involves this kind of interaction. [4]
Valence bond theory considers that the overlapping atomic orbitals of the participating atoms form a chemical bond. Because of the overlapping, it is most probable that electrons should be in the bond region. Valence bond theory views bonds as weakly coupled orbitals (small overlap). Valence bond theory is typically easier to employ in ground ...