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In chemistry, the law of mass action is the proposition that the rate of a chemical reaction is directly proportional to the product of the activities or concentrations of the reactants. [1] It explains and predicts behaviors of solutions in dynamic equilibrium .
At present, there is no single equation of state that accurately predicts the properties of all substances under all conditions. An example of an equation of state correlates densities of gases and liquids to temperatures and pressures, known as the ideal gas law, which is roughly accurate for weakly polar gases at low pressures and moderate temperatures.
One way to write the van der Waals equation is: [8] [9] [10] = where is pressure, is temperature, and = / is molar volume. In addition is the Avogadro constant, is the volume, and is the number of molecules (the ratio / is a physical quantity with base unit mole (symbol mol) in the SI).
The laws describing the behaviour of gases under fixed pressure, volume, amount of gas, and absolute temperature conditions are called gas laws.The basic gas laws were discovered by the end of the 18th century when scientists found out that relationships between pressure, volume and temperature of a sample of gas could be obtained which would hold to approximation for all gases.
The first constitutive equation (constitutive law) was developed by Robert Hooke and is known as Hooke's law.It deals with the case of linear elastic materials.Following this discovery, this type of equation, often called a "stress-strain relation" in this example, but also called a "constitutive assumption" or an "equation of state" was commonly used.
The first law of thermodynamics is essentially a definition of heat, i.e. heat is the change in the internal energy of a system that is not caused by a change of the external parameters of the system. However, the second law of thermodynamics is not a defining relation for the entropy.
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Coulomb's law has charge in place of mass and a different constant. Newton's law was later superseded by Albert Einstein 's theory of general relativity , but the universality of the gravitational constant is intact and the law still continues to be used as an excellent approximation of the effects of gravity in most applications.